Chiral isothiourea-catalyzed kinetic resolution of 4-hydroxy[2.2]paracyclophane.
acylation
kinetic resolution
nucleophilic catalysis
paracyclophanes
planar chirality
Journal
Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746
Informations de publication
Date de publication:
2021
2021
Historique:
received:
24
02
2021
accepted:
01
04
2021
entrez:
23
4
2021
pubmed:
24
4
2021
medline:
24
4
2021
Statut:
epublish
Résumé
We herein report a method for the kinetic resolution of racemic 4-hydroxy[2.2]paracyclophane by means of a chiral isothiourea-catalyzed acylation with isobutyric anhydride. This protocol allows for a reasonable synthetically useful
Identifiants
pubmed: 33889220
doi: 10.3762/bjoc.17.68
pmc: PMC8042488
doi:
Types de publication
Journal Article
Langues
eng
Pagination
800-804Subventions
Organisme : Austrian Science Fund FWF
ID : P 31784
Pays : Austria
Informations de copyright
Copyright © 2021, Weinzierl and Waser.
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