Kinetic-Model-Free Analysis of Transient Absorption Spectra Enabled by 2D Correlation Analysis.

Journal

The journal of physical chemistry letters
ISSN: 1948-7185
Titre abrégé: J Phys Chem Lett
Pays: United States
ID NLM: 101526034

Informations de publication

Date de publication:
06 May 2021
Historique:
pubmed: 24 4 2021
medline: 24 4 2021
entrez: 23 4 2021
Statut: ppublish

Résumé

Here, we present, to the best of our knowledge for the first time, a systematic study of utilizing 2D correlation analysis in the field of femtosecond transient absorption (fs-TA) spectroscopy. We present that the application of 2D correlation spectroscopy (2DCOS) to fs-TA spectroscopy enables a model-free means to analyze excited state kinetics, which is demonstrated on the model system [(tbbpy)

Identifiants

DOI: 10.1021/acs.jpclett.1c00835 PMID: 33890789
pubmed: 33890789
doi: 10.1021/acs.jpclett.1c00835
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

4148-4153

Auteurs

Julian Hniopek (J)

Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena, Germany.
Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743 Jena, Germany.
Friedrich Schiller University Jena, Abbe Center of Photonics, Albert-Einstein-Str. 6, 07745 Jena, Germany.

Carolin Müller (C)

Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena, Germany.
Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743 Jena, Germany.

Thomas Bocklitz (T)

Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena, Germany.
Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743 Jena, Germany.
Friedrich Schiller University Jena, Abbe Center of Photonics, Albert-Einstein-Str. 6, 07745 Jena, Germany.
ORCID: 0000-0003-2778-6624

Michael Schmitt (M)

Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743 Jena, Germany.
Friedrich Schiller University Jena, Abbe Center of Photonics, Albert-Einstein-Str. 6, 07745 Jena, Germany.
ORCID: 0000-0002-3807-3630

Benjamin Dietzek (B)

Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena, Germany.
Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743 Jena, Germany.
Friedrich Schiller University Jena, Abbe Center of Photonics, Albert-Einstein-Str. 6, 07745 Jena, Germany.
ORCID: 0000-0002-2842-3537

Jürgen Popp (J)

Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena, Germany.
Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743 Jena, Germany.
Friedrich Schiller University Jena, Abbe Center of Photonics, Albert-Einstein-Str. 6, 07745 Jena, Germany.
ORCID: 0000-0003-4257-593X

Classifications MeSH