Spontaneous Pillaring of Pentasil Zeolites.
catalysts
hierarchical materials
nanosheets
non-classical crystallization
zeolites
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Jun 2021
Jun 2021
Historique:
revised:
17
03
2021
received:
02
02
2021
pubmed:
28
4
2021
medline:
28
4
2021
entrez:
27
4
2021
Statut:
ppublish
Résumé
Conventional methods to prepare hierarchical zeolites depend upon the use of organic structure-directing agents and often require multiple synthesis steps with limited product yield and Brønsted acid concentration. Here, it is shown that the use of MEL- or MFI-type zeolites as crystalline seeds induces the spontaneous formation of self-pillared pentasil zeolites, thus avoiding the use of any organic or branching template for the crystallization of these hierarchical structures. The mechanism of formation is evaluated by time-resolved electron microscopy to provide evidence for the heterogeneous nucleation and growth of sequentially branched nanosheets from amorphous precursors. The resulting hierarchical zeolites have large external surface area and high percentages of external acid sites, which markedly improves their catalytic performance in the Friedel-Crafts alkylation and methanol to hydrocarbons reactions. These findings highlight a facile, commercially viable synthesis method to reduce mass-transport limitations and improve the performance of zeolite catalysts.
Identifiants
pubmed: 33904205
doi: 10.1002/adma.202100897
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2100897Subventions
Organisme : U.S. Department of Energy
ID : DE-SC0014468
Organisme : Welch Foundation
ID : E-1794
Organisme : European Commission
ID : H2020-MSCA-RISE-2019
Organisme : European Commission
ID : 872102
Organisme : Spanish MINECO and AEI/FEDER, UE throough project ref. RTI2018-099504-B-C21
Organisme : University of Alicante
ID : UATALENTO17-05
Informations de copyright
© 2021 Wiley-VCH GmbH.
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