Electrolytic synthesis of porphyrinic Zr-metal-organic frameworks with selective crystal topologies.

Journal

Dalton transactions (Cambridge, England : 2003)
ISSN: 1477-9234
Titre abrégé: Dalton Trans
Pays: England
ID NLM: 101176026

Informations de publication

Date de publication:
28 Apr 2021
Historique:
entrez: 28 4 2021
pubmed: 29 4 2021
medline: 29 4 2021
Statut: ppublish

Résumé

The thermodynamic (PCN-222) and kinetic (PCN-224) products of porphyrinic Zr-metal-organic frameworks (MOFs) were synthesized via an anodic dissolution approach for the first time. To the best of our knowledge, this is the first report of MOF polymorphs being controlled by electrolysis. The selective formation of PCN-222 requires an amorphous component to be present on the electrode during the initial reaction process.

Identifiants

DOI: 10.1039/d1dt00491c PMID: 33908962
pubmed: 33908962
doi: 10.1039/d1dt00491c
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

5411-5415

Auteurs

Keito Okada (K)

Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan. dtanaka@kwansei.ac.jp.

Yoko Tanaka (Y)

Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan. dtanaka@kwansei.ac.jp.

Tomoko Inose (T)

Research Institute for Electronic Science (RIES), Hokkaido University, N20W10, Sapporo 001-0020, Japan and Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
ORCID: 0000-0003-2757-8817

Hiroshi Ujii (H)

Research Institute for Electronic Science (RIES), Hokkaido University, N20W10, Sapporo 001-0020, Japan and Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee, 3001, Belgium.
ORCID: 0000-0002-0463-9659

Hirofumi Yoshikawa (H)

Department of Nanotechnology for Sustainable Energy, School of Science and Technology, Kwansei Gakuin University, Sanda, Hyogo 669-1337, Japan.
ORCID: 0000-0002-0088-1579

Daisuke Tanaka (D)

Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan. dtanaka@kwansei.ac.jp and Japan JST PRESTO, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan.
ORCID: 0000-0002-7469-0265

Classifications MeSH