Electrolyte Structure of Lithium Polysulfides with Anti-Reductive Solvent Shells for Practical Lithium-Sulfur Batteries.
electrolyte structure
lithium metal anode
lithium-sulfur batteries
polysulfide encapsulation
solvent shell
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
05 Jul 2021
05 Jul 2021
Historique:
received:
10
03
2021
pubmed:
30
4
2021
medline:
30
4
2021
entrez:
29
4
2021
Statut:
ppublish
Résumé
The lithium-sulfur (Li-S) battery is regarded as a promising secondary battery. However, constant parasitic reactions between the Li anode and soluble polysulfide (PS) intermediates significantly deteriorate the working Li anode. The rational design to inhibit the parasitic reactions is plagued by the inability to understand and regulate the electrolyte structure of PSs. Herein, the electrolyte structure of PSs with anti-reductive solvent shells was unveiled by molecular dynamics simulations and nuclear magnetic resonance. The reduction resistance of the solvent shell is proven to be a key reason for the decreased reactivity of PSs towards Li. With isopropyl ether (DIPE) as a cosolvent, DIPE molecules tend to distribute in the outer solvent shell due to poor solvating power. Furthermore, DIPE is more stable than conventional ether solvents against Li metal. The reactivity of PSs is suppressed by encapsulating PSs into anti-reductive solvent shells. Consequently, the cycling performance of working Li-S batteries was significantly improved and a pouch cell of 300 Wh kg
Identifiants
pubmed: 33913574
doi: 10.1002/anie.202103470
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
15503-15509Subventions
Organisme : National Natural Science Foundation of China
ID : 21825501 and U1801257
Organisme : National Key Research and Development Program
ID : 2016YFA0202500
Organisme : Discovery Grant from Natural Sciences and Engineering Research Council of Canada
ID : NSERC RGPIN-2017-05080
Informations de copyright
© 2021 Wiley-VCH GmbH.
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