Redox-Responsive Host-Guest Association between γ-Cyclodextrin and Mixed-Metal Keggin-Type Polyoxometalates.
Journal
Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543
Informations de publication
Date de publication:
17 May 2021
17 May 2021
Historique:
pubmed:
30
4
2021
medline:
30
4
2021
entrez:
29
4
2021
Statut:
ppublish
Résumé
The complexation of Keggin-type polyoxometalates (POMs) with γ-cyclodextrin (γ-CD) leads to supramolecular inclusion assemblies in aqueous solution driven by a chaotropic effect. The strength of the interaction between γ-CD and oxidized or one-electron reduced POMs in a series of molybdenum and vanadium monosubstituted phospho- and silico-tungstates, [XW
Identifiants
pubmed: 33915041
doi: 10.1021/acs.inorgchem.1c00724
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM