Quantification of N-terminal amyloid-β isoforms reveals isomers are the most abundant form of the amyloid-β peptide in sporadic Alzheimer's disease.

Alzheimer’s disease amyloid-β isomerization long-lived peptide mass spectrometry peptide

Journal

Brain communications
ISSN: 2632-1297
Titre abrégé: Brain Commun
Pays: England
ID NLM: 101755125

Informations de publication

Date de publication:
2021
Historique:
received: 05 11 2020
revised: 09 01 2021
accepted: 15 01 2021
entrez: 30 4 2021
pubmed: 1 5 2021
medline: 1 5 2021
Statut: epublish

Résumé

Plaques that characterize Alzheimer's disease accumulate over 20 years as a result of decreased clearance of amyloid-β peptides. Such long-lived peptides are subjected to multiple post-translational modifications, in particular isomerization. Using liquid chromatography ion mobility separations mass spectrometry, we characterized the most common isomerized amyloid-β peptides present in the temporal cortex of sporadic Alzheimer's disease brains. Quantitative assessment of amyloid-β N-terminus revealed that > 80% of aspartates (Asp-1 and Asp-7) in the N-terminus was isomerized, making isomerization the most dominant post-translational modification of amyloid-β in Alzheimer's disease brain. Total amyloid-β

Identifiants

pubmed: 33928245
doi: 10.1093/braincomms/fcab028
pii: fcab028
pmc: PMC8062259
doi:

Types de publication

Journal Article

Langues

eng

Pagination

fcab028

Informations de copyright

© The Author(s) (2021). Published by Oxford University Press on behalf of the Guarantors of Brain.

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Auteurs

Soumya Mukherjee (S)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.

Keyla A Perez (KA)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.

Larissa C Lago (LC)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.

Stephan Klatt (S)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.

Catriona A McLean (CA)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.
Department of Anatomical Pathology, Alfred Hospital, Prahran, VIC 3004, Australia.

Ian E Birchall (IE)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.

Kevin J Barnham (KJ)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.

Colin L Masters (CL)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.

Blaine R Roberts (BR)

Florey Institute of Neuroscience and Mental Health, University of Melbourne, Melbourne, VIC 3010, Australia.
Department of Biochemistry, Emory University School of Medicine, Atlanta, GA 30322, USA.
Department of Neurology, Emory University School of Medicine, Atlanta, GA 30322, USA.

Classifications MeSH