Spatially Resolved Kinetic Model of Parahydrogen Induced Polarisation (PHIP) in a Microfluidic Chip.
NMR spectroscopy
finite element modelling
homogeneous catalysis
kinetics
microfluidics
Journal
Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN: 1439-7641
Titre abrégé: Chemphyschem
Pays: Germany
ID NLM: 100954211
Informations de publication
Date de publication:
05 10 2021
05 10 2021
Historique:
revised:
23
04
2021
received:
18
02
2021
pubmed:
1
5
2021
medline:
1
5
2021
entrez:
30
4
2021
Statut:
ppublish
Résumé
We report a spatially resolved kinetic finite element model of parahydrogen-induced polarisation (PHIP) in a microfluidic chip that was calibrated using on-chip and off-chip NMR data. NMR spectroscopy has great potential as a read-out technique for lab-on-a-chip (LoC) devices, but is often limited by sensitivity. By integrating PHIP with a LoC device, a continuous stream of hyperpolarised material can be produced, and mass sensitivities of
Identifiants
pubmed: 33929791
doi: 10.1002/cphc.202100135
pmc: PMC8518753
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
2004-2013Subventions
Organisme : iCASE
Organisme : SJO from EPSRC
Organisme : Bruker UK Ltd
Informations de copyright
© 2021 The Authors. ChemPhysChem published by Wiley-VCH GmbH.
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