Detailed chemical characterization of the composition and variability of soil gas at remediated residential heating oil discharges.

Underground storage tanks containing petroleum or other hazardous substances are used widely for residential storage of home heating oil. Spills and leaks of fuel from these tanks are common, and resulting subsurface petroleum vapors may pose health risks. However, understanding of this risk is limited by a lack of observational data on the chemical composition of vapors from discharged fuel. We present here the composition of soil gas sampled at 66 remediated residential sites of underground heating oil discharges throughout Virginia using a newly developed data analysis technique that allows characterization of hydrocarbons by carbon number and degree of unsaturation. Measured concentrations of total petroleum hydrocarbons exceeded 100,000 μg/m

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