Direct Synthesis of Nanosheet-Stacked Hierarchical "Honey Stick-like" MFI Zeolites by an Aromatic Heterocyclic Dual-Functional Organic Structure-Directing Agent.

Heterocycles MFI zeolites nanosheets self-assembly stacking interactions

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
16 Jun 2021
Historique:
received: 25 02 2021
pubmed: 4 5 2021
medline: 4 5 2021
entrez: 3 5 2021
Statut: ppublish

Résumé

Soft template designing is the most promising strategy for the synthesis of zeolite nanosheets. MFI nanosheets directed by soft templates (containing long-chain alkyl groups or aromatic groups as hydrophobic component) can be found frequently; however, so far, MFI nanosheets synthesized by soft templates with aromatic heterocycle groups (e. g., s-triazine groups) are rare. Herein, a nanosheet-stacked hierarchical MFI zeolite (NSHM) has been synthesized by using a triply branched s-triazine-based surfactant as a bifunctional organic structure-directing agent. On the basis of a geometrical match relationship, a formation model has been proposed. Synthesized NSHM had abundant mesopores stacked by nanosheets and exhibited a high surface area (430 m

Identifiants

pubmed: 33938064
doi: 10.1002/chem.202100701
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

8694-8697

Subventions

Organisme : Innovative Research Group Project of the National Natural Science Foundation of China
ID : 21776311
Organisme : Innovative Research Group Project of the National Natural Science Foundation of China
ID : 51601223
Organisme : Natural Science Foundation of Shandong Province
ID : ZR2016BM28
Organisme : International Science and Technology Cooperation Programme
ID : 2018YFE0118200
Organisme : Key Technology Research and Development Program of Shandong
ID : 2019JZZY010506
Organisme : Fundamental Research Funds for the Central Universities
ID : 15CX05030A

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Risheng Wang (R)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Zhihua Peng (Z)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Pingping Wu (P)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Jinzhi Lu (J)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Mark J Rood (MJ)

Department of Civil and Environmental Engineering, University of Illinois, 205 North Mathews Avenue, Urbana, Illinois, 61801, United States.

Hongman Sun (H)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Jingbin Zeng (J)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Youhe Wang (Y)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Zifeng Yan (Z)

College of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum (EastChina), No. 66, Changjiang West Road Qingdao Economic & Technical Development Zone, Qingdao, 266580, Shandong, P. R. China.

Classifications MeSH