Fluorine-18 labelled Ruppert-Prakash reagent ([


Journal

Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838

Informations de publication

Date de publication:
27 May 2021
Historique:
pubmed: 5 5 2021
medline: 5 5 2021
entrez: 4 5 2021
Statut: ppublish

Résumé

This article describes the first synthesis and application of fluorine-18 labelled Ruppert-Prakash reagent [18F]Me3SiCF3. [18F]Me3SiCF3 was synthesized from [18F]fluoroform with radiochemical yields of 85-95% and radiochemical purities of >95% within 20 minutes. 18F-trifluoromethylated compounds were successfully prepared by reaction of [18F]Me3SiCF3 with benzaldehydes, acetophenones and benzophenones.

Identifiants

pubmed: 33942818
doi: 10.1039/d1cc01789f
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

5286-5289

Auteurs

Anna Pees (A)

Amsterdam UMC, VU University, Radiology and Nuclear medicine, Radionuclide Center, De Boelelaan 1085c, Amsterdam, The Netherlands. d.vugts@amsterdamumc.nl.

Maria J W D Vosjan (MJWD)

BV Cyclotron VU, De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands.

Neil Vasdev (N)

Azrieli Centre for Neuro-Radiochemistry, Brain Health Imaging Centre, Centre for Addiction and Mental Health & Department of Psychiatry, University of Toronto, 250 College St., Toronto M5T-1R8, ON, Canada.

Albert D Windhorst (AD)

Amsterdam UMC, VU University, Radiology and Nuclear medicine, Radionuclide Center, De Boelelaan 1085c, Amsterdam, The Netherlands. d.vugts@amsterdamumc.nl.

Danielle J Vugts (DJ)

Amsterdam UMC, VU University, Radiology and Nuclear medicine, Radionuclide Center, De Boelelaan 1085c, Amsterdam, The Netherlands. d.vugts@amsterdamumc.nl.

Classifications MeSH