A versatile iodo(III)etherification of terminal ethynylsilanes using BF
Journal
Organic & biomolecular chemistry
ISSN: 1477-0539
Titre abrégé: Org Biomol Chem
Pays: England
ID NLM: 101154995
Informations de publication
Date de publication:
05 05 2021
05 05 2021
Historique:
entrez:
5
5
2021
pubmed:
6
5
2021
medline:
6
5
2021
Statut:
ppublish
Résumé
A series of (E)-α-silyl-β-alkoxyvinyl-λ3-iodanes was synthesized from iodosylbenzene, BF3-ether complexes, and terminal ethynylsilanes. The combined use of BF3-OiPr2 and benzyl ethers of primary alcohols (ROBn) allows the chemoselective transfer of primary alkoxy groups (RO) onto the β-position of the terminal ethynylsilanes.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM