Electrically Induced Mixed Valence Increases the Conductivity of Copper Helical Metallopolymers.

chirality metallopolymers mixed-valency resistive switching self-assembly

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Jun 2021
Historique:
revised: 11 03 2021
received: 16 01 2021
pubmed: 7 5 2021
medline: 7 5 2021
entrez: 6 5 2021
Statut: ppublish

Résumé

Controlling the flow of electrical current at the nanoscale typically requires complex top-down approaches. Here, a bottom-up approach is employed to demonstrate resistive switching within molecular wires that consist of double-helical metallopolymers and are constructed by self-assembly. When the material is exposed to an electric field, it is determined that ≈25% of the copper atoms oxidize from Cu

Identifiants

pubmed: 33955595
doi: 10.1002/adma.202100403
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2100403

Subventions

Organisme : UK Engineering and Physical Sciences Research Council
ID : EPSRC EP/P027067/1
Organisme : UK Engineering and Physical Sciences Research Council
ID : EP/M01083x/1
Organisme : UK Engineering and Physical Sciences Research Council
ID : EP/M005143/1
Organisme : ERC Synergy
ID : 610115
Organisme : European Research Council
ID : ERC695009
Pays : International

Informations de copyright

© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.

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Auteurs

Jake L Greenfield (JL)

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.

Daniele Di Nuzzo (D)

Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, UK.

Emrys W Evans (EW)

Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, UK.

Satyaprasad P Senanayak (SP)

Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, UK.

Sam Schott (S)

Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, UK.

Jason T Deacon (JT)

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.

Adele Peugeot (A)

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.

William K Myers (WK)

Centre for Advanced ESR, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK.

Henning Sirringhaus (H)

Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, UK.

Richard H Friend (RH)

Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, UK.

Jonathan R Nitschke (JR)

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.

Classifications MeSH