Fast and simultaneous analysis of carbamate pesticides and anticoagulant rodenticides used in suspected cases of animal poisoning.

Animal poisoning Anticoagulant rodenticide Carbamate pesticide High resolution MS Orbitrap QuEChERS Retrospective analysis

Journal

Forensic science international
ISSN: 1872-6283
Titre abrégé: Forensic Sci Int
Pays: Ireland
ID NLM: 7902034

Informations de publication

Date de publication:
28 Apr 2021
Historique:
received: 18 12 2020
revised: 19 04 2021
accepted: 21 04 2021
pubmed: 11 5 2021
medline: 11 5 2021
entrez: 10 5 2021
Statut: aheadofprint

Résumé

Carbamate pesticides (CBs) are reported as one of the main causes of intentional or accidental poisoning of animals. Anticoagulant rodenticides (ARs) form the main class of poisons implicated in analyzed poisoned baits. These two groups of pesticide compounds include multiple substances, and thus, the development of a simple and rapid multiclass/multiresidue analytical method for simultaneous identification of both toxicant classes should be a useful strategy for analytical laboratories to reduce analysis time and cost. The present study aimed to elaborate and validate a rapid method to simultaneously determine 11 CBs and 8 ARs in samples of real matrices (bait, stomach content, and liver) from suspected animal poisoning cases. QuEChERS sample treatment and liquid chromatography coupled to hybrid high resolution mass spectrometry were used. The method resulted in good linearity (R

Identifiants

pubmed: 33971506
pii: S0379-0738(21)00130-4
doi: 10.1016/j.forsciint.2021.110810
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

110810

Informations de copyright

Copyright © 2021 The Author(s). Published by Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Federica Gallocchio (F)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy. Electronic address: fgallocchio@izsvenezie.it.

Alessandra Moressa (A)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Roberto Stella (R)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Roberta Rosin (R)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Lara Basilicata (L)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Laura Bille (L)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Marica Toson (M)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Giancarlo Biancotto (G)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Francesca Lega (F)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Roberto Angeletti (R)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Giovanni Binato (G)

Istituto Zooprofilattico Sperimentale delle Venezie, Legnaro (Padova), Italy.

Classifications MeSH