An Ultra-Long-Lived Triplet Excited State in Water at Room Temperature: Insights on the Molecular Design of Tridecafullerenes.
fullerenes
glycoconjugates
photochemistry
triplet lifetime
triplet quenching
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
12 Jul 2021
12 Jul 2021
Historique:
revised:
27
04
2021
received:
25
03
2021
pubmed:
14
5
2021
medline:
14
5
2021
entrez:
13
5
2021
Statut:
ppublish
Résumé
Suitably engineered molecular systems exhibiting triplet excited states with very long lifetimes are important for high-end applications in nonlinear optics, photocatalysis, or biomedicine. We report the finding of an ultra-long-lived triplet state with a mean lifetime of 93 ms in an aqueous phase at room temperature, measured for a globular tridecafullerene with a highly compact glycodendrimeric structure. A series of three tridecafullerenes bearing different glycodendrons and spacers to the C
Identifiants
pubmed: 33984168
doi: 10.1002/anie.202104223
pmc: PMC8361972
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
16109-16118Subventions
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : CTQ2017-84327-P
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : CTQ2017-83531-R
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : CTQ2017-87269-P
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : CTQ2017-86265-P
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : CTQ2015-71896-REDT
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : CTQ2016-78454-C2-1-R
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : FPU fellowship
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : SEV-2016-0686
Organisme : Generalitat de Catalunya
ID : 2017SGR629
Organisme : Generalitat de Catalunya
ID : 2017 FI_B 00617 and 2018 FI_B1 00174
Organisme : Institució Catalana de Recerca i Estudis Avançats
ID : ICREA ACADEMIA
Informations de copyright
© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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