The Role of Nitrogen-doping in the Catalytic Transfer Hydrogenation of Phenol to Cyclohexanone with Formic Acid over Pd supported on Carbon Nanotubes.
Deactivation
N-doping
formic acid decomposition
nonplanar adsorption
transfer hydrogenation
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
26 Jul 2021
26 Jul 2021
Historique:
received:
17
03
2021
pubmed:
18
5
2021
medline:
18
5
2021
entrez:
17
5
2021
Statut:
ppublish
Résumé
Highly selective one-step hydrogenation of phenol to cyclohexanone, an important intermediate in the production of nylon 6 and nylon 66, is desirable but remains a challenge. Pd nanoparticles supported on nitrogen- and oxygen-functionalized carbon nanotubes (NCNTs, OCNTs) were prepared, characterized, and applied in the hydrogenation of phenol to cyclohexanone to study the effect of N-doping. Almost full conversion of phenol with high selectivity to cyclohexanone was achieved over Pd/NCNT under mild reaction conditions using either H
Identifiants
pubmed: 33998733
doi: 10.1002/chem.202100981
pmc: PMC8361974
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
10948-10956Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : MU 1327/10-1
Organisme : Research Department Closed Carbon Cycle Economy (CCCE) at the Ruhr-University Bochum
Informations de copyright
© 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.
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