Small rings in the bigger picture: ring expansion of three- and four-membered rings to access larger all-carbon cyclic systems.
Journal
Chemical Society reviews
ISSN: 1460-4744
Titre abrégé: Chem Soc Rev
Pays: England
ID NLM: 0335405
Informations de publication
Date de publication:
07 Jul 2021
07 Jul 2021
Historique:
pubmed:
19
5
2021
medline:
19
5
2021
entrez:
18
5
2021
Statut:
ppublish
Résumé
The release of the inherent ring strain of cyclobutane and cyclopropane derivatives allows a rapid build-up of molecular complexity. This review highlights the state-of-the-art of the ring expansions of three- and four-membered cycles and is organised by types of reactions with emphasis on the reaction mechanisms. Selected examples are discussed to illustrate the synthetic potential of this elegant synthetic tool.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM