Small rings in the bigger picture: ring expansion of three- and four-membered rings to access larger all-carbon cyclic systems.


Journal

Chemical Society reviews
ISSN: 1460-4744
Titre abrégé: Chem Soc Rev
Pays: England
ID NLM: 0335405

Informations de publication

Date de publication:
07 Jul 2021
Historique:
pubmed: 19 5 2021
medline: 19 5 2021
entrez: 18 5 2021
Statut: ppublish

Résumé

The release of the inherent ring strain of cyclobutane and cyclopropane derivatives allows a rapid build-up of molecular complexity. This review highlights the state-of-the-art of the ring expansions of three- and four-membered cycles and is organised by types of reactions with emphasis on the reaction mechanisms. Selected examples are discussed to illustrate the synthetic potential of this elegant synthetic tool.

Identifiants

pubmed: 34002179
doi: 10.1039/d0cs01396j
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

7513-7538

Auteurs

Bohdan Biletskyi (B)

Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France. gaelle.chouraqui@univ-amu.fr.

Pierre Colonna (P)

Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France. gaelle.chouraqui@univ-amu.fr.

Kévin Masson (K)

Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France. gaelle.chouraqui@univ-amu.fr.

Jean-Luc Parrain (JL)

Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France. gaelle.chouraqui@univ-amu.fr.

Laurent Commeiras (L)

Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France. gaelle.chouraqui@univ-amu.fr.

Gaëlle Chouraqui (G)

Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Marseille, France. gaelle.chouraqui@univ-amu.fr.

Classifications MeSH