A dual-channel optical chemical sensing system for selective detection of nerve agent simulant DFP.
Chemical sensing
DFP
Dual channel
Nerve agent
Self-immolation
Journal
Analytical and bioanalytical chemistry
ISSN: 1618-2650
Titre abrégé: Anal Bioanal Chem
Pays: Germany
ID NLM: 101134327
Informations de publication
Date de publication:
Jul 2021
Jul 2021
Historique:
received:
16
03
2021
accepted:
17
05
2021
revised:
10
05
2021
pubmed:
28
5
2021
medline:
28
5
2021
entrez:
27
5
2021
Statut:
ppublish
Résumé
This paper reports a novel optical chemical sensing system for selective detection of diisopropylfluorophosphate (DFP), a simulant of fluorine-containing nerve agents (Sarin and Soman). Contrary to the reported methods involving only single sensing probe, this sensing system is comprised of two molecular sensing probes (1 and 2) having intrinsic affinities for reactive subunits of DFP (electrophilic phosphorus and fluoride ion). On exposure to DFP, two molecular probes react in tandem with electrophilic phosphorus and fluoride ion (by-product of the initial phosphorylation reaction) to induce a unique modulation in the optical properties of the sensing system which leads to selective detection of DFP in solution as interferents like phosphorus-containing compounds, acids, and anions were unable to induce similar optical modulation due to lack of both electrophilic phosphorus and fluorine in the same molecule. Calibration curve between the amount of DFP added and the absorption intensity revealed the colorimetric detection limit of the system to be 4.50 μM which was further lowered to 2.22 μM by making use of a self-immolative fluoride sensing probe 5.
Identifiants
pubmed: 34041577
doi: 10.1007/s00216-021-03413-5
pii: 10.1007/s00216-021-03413-5
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4501-4509Références
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