A Polar and Ordered-Channel Composite Separator Enables Antidendrite and Long-Cycle Lithium Metal Batteries.

Lithium (Li) metal as an anode replacing the traditional graphite could largely enhance the specific energy density of Li batteries. However, the repeated formation of solid electrolyte interfaces on the surface of Li metal upon plating/stripping leads to a low Coulombic efficiency, and the growth of Li dendrites upon cycling probably causes the short circuit or even explosion of the batteries, both of which block the commercial application of Li metal in lithium metal batteries (LMBs). Herein, we report an antidendrite AAO@PVDF-HFP composite separator fabricated by a two-step method, which features the ordered pore channels and the polar groups in the channels. This novel composite separator has a good wettability to the electrolyte, high mechanical properties, and high ionic conductivity. Expectedly, the assembled batteries based on our novel composite separator show many impressive performances. In Li-Li cells, the cycling life up to 1600 h at an areal current density of 2 mA/cm