Synthesis of 1,1-Diboryl Alkenes Using the Boryl-Heck Reaction.

Alkenes / chemical synthesis Molecular Structure Stereoisomerism

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
18 06 2021
Historique:
pubmed: 28 5 2021
medline: 16 11 2021
entrez: 27 5 2021
Statut: ppublish

Résumé

The synthesis of 1,1-diboryl alkenes from terminal alkenes is reported. 1,1-Regioselective addition is observed for both conjugated and unconjugated alkenes, allowing for a single method to prepare a wide range of 1,1-diboryl alkenes.

Identifiants

DOI: 10.1021/acs.orglett.1c01567 PMID: 34043367 PMC: PMC8217338
pubmed: 34043367
doi: 10.1021/acs.orglett.1c01567
pmc: PMC8217338
mid: NIHMS1709119
doi:

Substances chimiques

Alkenes 0

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

4838-4842

Subventions

Organisme : NIGMS NIH HHS
ID : P20 GM104316
Pays : United States
Organisme : NIGMS NIH HHS
ID : P30 GM110758
Pays : United States
Organisme : NIH HHS
ID : S10 OD016267
Pays : United States
Organisme : NCRR NIH HHS
ID : S10 RR026962
Pays : United States

Références

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Auteurs

Olamide O Idowu (OO)

Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States.

Jacob C Hayes (JC)

Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States.

William B Reid (WB)

Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States.

Donald A Watson (DA)

Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
ORCID: 0000-0003-4864-297X

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures acycliques › Alcènes › Synthesis of 1,1-Diboryl Alkenes Using the...
questionsmedicales.fr › Phénomènes chimiques › Structure moléculaire › Synthesis of 1,1-Diboryl Alkenes Using the...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes de chimie organique › Isomérie › Stéréoisomérie › Synthesis of 1,1-Diboryl Alkenes Using the...