Facet Selectivity Guided Assembly of Nanoarchitectures onto Two-Dimensional Metal-Organic Framework Nanosheets.

anti-counterfeiting facet selectivity metal-organic frameworks two dimensional structures upconversion

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
02 08 2021
Historique:
received: 10 03 2021
pubmed: 30 5 2021
medline: 30 5 2021
entrez: 29 5 2021
Statut: ppublish

Résumé

Facet-selective nanostructures in living systems usually exhibit outstanding optical and enzymatic properties, playing important roles in photonics, matter exchange, and biocatalysis. Bioinspired construction of facet-selective nanostructures offers great opportunities for sophisticated nanomaterials, but remains a formidable task. We have developed a macromolecule-mediated strategy for the assembly of upconversion nanoparticles (UCNPs)/two-dimensional metal-organic frameworks (2DMOFs) heterostructures with facet selectivity. Both experimental and theoretical results demonstrate that polyvinylpyrrolidone (PVP) can be utilized as an interface-selective mediator to further promote the facet-selective assembly of MOFs onto the surface of UCNPs. The UCNPs/2DMOFs nanostructures with facet selectivity display specific optical properties and show great advantages in anti-counterfeiting. Our demonstration of UCNPs/2DMOFs provides a vivid example for the controlled fabrication of facet-selective nanostructures and can promote the development of advanced functional materials for applications in biosensing, energy conversion, and information assurance.

Identifiants

pubmed: 34050591
doi: 10.1002/anie.202103486
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

17564-17569

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Zhihao Li (Z)

Key Laboratory of Biomedical Polymers of Ministry of Education, College of Chemistry and Molecular Sciences, School of Microelectronics, Wuhan University, Wuhan, 430072, China.

Huajian Gao (H)

Key Laboratory of Biomedical Polymers of Ministry of Education, College of Chemistry and Molecular Sciences, School of Microelectronics, Wuhan University, Wuhan, 430072, China.

Ruichen Shen (R)

Institute of Chemical Biology and Nanomedicine, State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.

Caixin Zhang (C)

Department of Applied Physics, School of Physics and Electronics, Hunan University, Changsha, 410082, China.

Leisi Li (L)

Key Laboratory of Biomedical Polymers of Ministry of Education, College of Chemistry and Molecular Sciences, School of Microelectronics, Wuhan University, Wuhan, 430072, China.

Yawei Lv (Y)

Department of Applied Physics, School of Physics and Electronics, Hunan University, Changsha, 410082, China.

Liming Tang (L)

Department of Applied Physics, School of Physics and Electronics, Hunan University, Changsha, 410082, China.

Yaping Du (Y)

School of Materials Science and Engineering & National Institute for Advanced Materials, Key Laboratory of Advanced Energy Materials Chemistry, Tianjin Key Lab for Rare Earth Materials and Applications, Centre for Rare Earth and Inorganic Functional Materials, Nankai University, Tianjin, 300350, China.

Quan Yuan (Q)

Key Laboratory of Biomedical Polymers of Ministry of Education, College of Chemistry and Molecular Sciences, School of Microelectronics, Wuhan University, Wuhan, 430072, China.
Institute of Chemical Biology and Nanomedicine, State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China.

Classifications MeSH