Ultrathin two-dimensional conjugated metal-organic framework single-crystalline nanosheets enabled by surfactant-assisted synthesis.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
21 Apr 2020
21 Apr 2020
Historique:
entrez:
7
6
2021
pubmed:
21
4
2020
medline:
21
4
2020
Statut:
epublish
Résumé
Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) have recently emerged for potential applications in (opto-)electronics, chemiresistive sensing, and energy storage and conversion, due to their excellent electrical conductivity, abundant active sites, and intrinsic porous structures. However, developing ultrathin 2D c-MOF nanosheets (NSs) for facile solution processing and integration into devices remains a great challenge, mostly due to unscalable synthesis, low yield, limited lateral size and low crystallinity. Here, we report a surfactant-assisted solution synthesis toward ultrathin 2D c-MOF NSs, including HHB-Cu (HHB = hexahydroxybenzene), HHB-Ni and HHTP-Cu (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene). For the first time, we achieve single-crystalline HHB-Cu(Ni) NSs featured with a thickness of 4-5 nm (∼8-10 layers) and a lateral size of 0.25-0.65 μm
Identifiants
pubmed: 34094144
doi: 10.1039/d0sc01408g
pii: d0sc01408g
pmc: PMC8159486
doi:
Types de publication
Journal Article
Langues
eng
Pagination
7665-7671Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
Références
Nat Mater. 2003 Mar;2(3):190-5
pubmed: 12612678
Chem Commun (Camb). 2011 Aug 7;47(29):8436-8
pubmed: 21709877
Angew Chem Int Ed Engl. 2019 Jul 29;58(31):10677-10682
pubmed: 31169942
J Am Chem Soc. 2015 Feb 18;137(6):2235-8
pubmed: 25651395
Adv Mater. 2015 Dec 2;27(45):7372-8
pubmed: 26468970
Adv Mater. 2018 Jun;30(26):e1707234
pubmed: 29774609
J Am Chem Soc. 2013 Feb 20;135(7):2462-5
pubmed: 23360513
Adv Mater. 2020 Jan;32(4):e1905361
pubmed: 31815328
J Am Chem Soc. 2014 Jun 25;136(25):8859-62
pubmed: 24750124
Nat Mater. 2010 Jul;9(7):565-71
pubmed: 20512155
J Am Chem Soc. 2019 Jan 9;141(1):53-57
pubmed: 30580521
Nat Commun. 2015 Jun 15;6:7408
pubmed: 26074272
Adv Mater. 2016 Jun;28(21):4149-55
pubmed: 27008574
Science. 2014 Dec 12;346(6215):1356-9
pubmed: 25504718
Nat Mater. 2018 Nov;17(11):1027-1032
pubmed: 30323335
Chem Soc Rev. 2018 Aug 13;47(16):6267-6295
pubmed: 29971309
Sci Adv. 2018 Jun 29;4(6):eaat1817
pubmed: 29963633
Science. 2002 Jan 18;295(5554):469-72
pubmed: 11799235
J Am Chem Soc. 2018 Aug 15;140(32):10315-10323
pubmed: 30041519
J Am Chem Soc. 2014 Nov 19;136(46):16112-5
pubmed: 25365211
ACS Appl Mater Interfaces. 2018 May 2;10(17):15012-15020
pubmed: 29658262
Nat Commun. 2018 Jun 19;9(1):2401
pubmed: 29921871
Science. 2019 Nov 22;366(6468):
pubmed: 31753970
Angew Chem Int Ed Engl. 2018 Jul 16;57(29):8886-8890
pubmed: 29675949
Nat Commun. 2017 Jun 05;8:15341
pubmed: 28580963
ACS Cent Sci. 2019 Dec 26;5(12):1959-1964
pubmed: 31893225
J Am Chem Soc. 2018 Nov 7;140(44):14533-14537
pubmed: 30176142
Adv Mater. 2017 Aug;29(32):
pubmed: 28634989