Sulphur-Embedded Hydrocarbon Belts: Synthesis, Structure and Redox Chemistry of Cyclothianthrenes.
Möbius strip
cyclacene
hydrocarbon belt
macrocycle
thianthrene
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
16 Aug 2021
16 Aug 2021
Historique:
revised:
07
05
2021
received:
22
03
2021
pubmed:
11
6
2021
medline:
11
6
2021
entrez:
10
6
2021
Statut:
ppublish
Résumé
Cyclothianthrenes, a series of sulphur-embedded hydrocarbon belts proposed a decade ago, were successfully constructed through a stepwise bottom-up synthesis. The belt [6]cyclothianthrene ([6]CT) is the smallest and most strained member of the family yet reported. Both [6]CT and [8]CT are the first examples of cyclothianthrene characterized by single crystal X-ray diffraction. An unprecedented chiral belt [7]CT and a Möbius-shaped [9]CT were also achieved via modular synthesis. Crystallographic and computational studies show that belts [6]CT-[8]CT have prism-like conformations with well-defined tubular cavities which have potential for guest molecule inclusion. Cyclic voltammograms further revealed that these belts are redox-active. The success of constructing sulphur-embedded hydrocarbon belts, that is, cyclothianthrenes, greatly enriches the chemistry of heteroatom-doped molecular belts and tubes.
Identifiants
pubmed: 34110693
doi: 10.1002/anie.202104054
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
18443-18447Subventions
Organisme : National Natural Science Foundation of China
ID : 21701192
Organisme : National Natural Science Foundation of China
ID : 21971268
Organisme : National Natural Science Foundation of China
ID : 51903254
Organisme : Fundamental Research Funds for the Central Universities
ID : 19lgzd22
Organisme : Program for Guangdong Introducing Innovative and Entrepreneurial Teams
ID : 2017ZT07C069
Informations de copyright
© 2021 Wiley-VCH GmbH.
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