Identification and composition of carbonate minerals of the calcite structure by Raman and infrared spectroscopies using portable devices.

Carbonate minerals Infrared spectroscopy Portable spectrometers Qualitative analysis Raman spectroscopy

Journal

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
ISSN: 1873-3557
Titre abrégé: Spectrochim Acta A Mol Biomol Spectrosc
Pays: England
ID NLM: 9602533

Informations de publication

Date de publication:
15 Nov 2021
Historique:
received: 09 02 2021
revised: 20 04 2021
accepted: 17 05 2021
pubmed: 12 6 2021
medline: 6 7 2021
entrez: 11 6 2021
Statut: ppublish

Résumé

A portable Raman device with a 532 nm excitation laser and a portable infrared spectrometer with ATR (Attenuated Total Reflection) mode were used to analyse the spectral features associated with the identification and compositional variation of Ca-Mg-Fe-Mn natural carbonate minerals with a calcite structure (calcite, ankerite, dolomite, siderite, rhodochrosite, and magnesite). A systematic study of the variations of the peak positions with various compositional ratios was carried out. Most of the band positions were shifted to lower wavenumbers with increasing ionic radius or atomic mass of the divalent cations but the band of the translational lattice (T) mode in Raman and the symmetric bending (ν

Identifiants

pubmed: 34116416
pii: S1386-1425(21)00557-6
doi: 10.1016/j.saa.2021.119980
pii:
doi:

Substances chimiques

Carbonates 0
Minerals 0
Calcium Carbonate H0G9379FGK

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

119980

Informations de copyright

Copyright © 2021 The Author(s). Published by Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Yonghwi Kim (Y)

GeoRessources Laboratory -Université de Lorraine, Faculté des Sciences et Technologies, BP 70239, F-54506 Vandœuvre-lès-Nancy, France. Electronic address: yonghwi.kim@univ-lorraine.fr.

Marie-Camille Caumon (MC)

GeoRessources Laboratory -Université de Lorraine, Faculté des Sciences et Technologies, BP 70239, F-54506 Vandœuvre-lès-Nancy, France.

Odile Barres (O)

GeoRessources Laboratory -Université de Lorraine, Faculté des Sciences et Technologies, BP 70239, F-54506 Vandœuvre-lès-Nancy, France.

Amadou Sall (A)

GeoRessources Laboratory -Université de Lorraine, Faculté des Sciences et Technologies, BP 70239, F-54506 Vandœuvre-lès-Nancy, France.

Jean Cauzid (J)

GeoRessources Laboratory -Université de Lorraine, Faculté des Sciences et Technologies, BP 70239, F-54506 Vandœuvre-lès-Nancy, France.

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Classifications MeSH