Physico-chemical characterization of bilirubin-10-sulfonate and comparison of its acid-base behavior with unconjugated bilirubin.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
18 06 2021
Historique:
received: 11 01 2021
accepted: 09 06 2021
entrez: 19 6 2021
pubmed: 20 6 2021
medline: 20 6 2021
Statut: epublish

Résumé

Unconjugated bilirubin (UCB) is the end-product of heme catabolism in the intravascular compartment. Although beneficial for human health when mildly elevated in the body, when present at greater than a critical threshold concentration, UCB exerts toxic effects that are related to its physico-chemical properties, particularly affecting the central nervous system. The aim of the present study was to characterize bilirubin-10-sulfonate (ranarubin), a naturally occurring bile pigment, including determination of its mixed acidity constants (pK

Identifiants

pubmed: 34145377
doi: 10.1038/s41598-021-92377-8
pii: 10.1038/s41598-021-92377-8
pmc: PMC8213708
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

12896

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Auteurs

Adam Čepa (A)

Department of Organic Chemistry, Faculty of Science, Charles University, Prague, Czech Republic.

Veronika Dejmková (V)

Department of Organic Chemistry, Faculty of Science, Charles University, Prague, Czech Republic.

Ladislav Lešetický (L)

Department of Organic Chemistry, Faculty of Science, Charles University, Prague, Czech Republic.

Ivan Jelínek (I)

Department of Organic Chemistry, Faculty of Science, Charles University, Prague, Czech Republic.

Stanislav Smrček (S)

Department of Organic Chemistry, Faculty of Science, Charles University, Prague, Czech Republic.

Martin Štícha (M)

Department of Organic Chemistry, Faculty of Science, Charles University, Prague, Czech Republic.

Jana Jašprová (J)

Institute of Medical Biochemistry and Laboratory Diagnostics, 1st Faculty of Medicine, Charles University, Na Bojišti 3, Praha 2, 12000, Czech Republic.

Marie Urbanová (M)

University of Chemistry and Technology, Prague, Czech Republic.

Iryna Goncharova (I)

University of Chemistry and Technology, Prague, Czech Republic.

Martin Dračínský (M)

Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Prague, Czech Republic.

Eliška Procházková (E)

Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Prague, Czech Republic.

Donald J Ostrow (DJ)

GI/Hepatology Division, University of Washington School of Medicine, Seattle, WA, USA.

Libor Vítek (L)

Institute of Medical Biochemistry and Laboratory Diagnostics, 1st Faculty of Medicine, Charles University, Na Bojišti 3, Praha 2, 12000, Czech Republic. vitek@cesnet.cz.
4th Department of Internal Medicine, 1st Faculty of Medicine, Charles University, Prague, Czech Republic. vitek@cesnet.cz.

Classifications MeSH