A spectroscopic approach for rapid and simple serial number restoration on polyamide 6 parts of firearms: The use of video spectral comparator 8000.

UV/infrared lights non-destructive restoration obliteration polymer serial numbers spectral imaging

Journal

Journal of forensic sciences
ISSN: 1556-4029
Titre abrégé: J Forensic Sci
Pays: United States
ID NLM: 0375370

Informations de publication

Date de publication:
Nov 2021
Historique:
revised: 02 05 2021
received: 16 03 2021
accepted: 24 05 2021
pubmed: 20 6 2021
medline: 20 6 2021
entrez: 19 6 2021
Statut: ppublish

Résumé

Serial numbers have forensic value as they help to identify firearms. While the serial numbers are mostly stamped on the metal parts of firearms, the characters on polymer parts involve non-serial number information such as caliber, brand, model, or proof marks, which also serve for identification purposes. The forensic evidence indicates that the polymer frames of firearms bearing non-serial number information are obliterated through heating and scraping. Although the destructive restoration techniques for polymers are well-documented, there is little theoretical and practical knowledge regarding the non-destructive restoration techniques applied on polymers. In view of this gap, this study aims to devise a non-destructive spectral technique to recover the obliterated characters on Polyamide 6. Considering its wide use on polymers, the numbering is carried out by hot stamping and the numbers are defaced through heating, scraping, and hammering both superficially and deeply at varying depths. Herein, we focused on imitating the manual obliteration techniques used by criminals instead of the deepness-controlled techniques preferred by previous studies. The samples are then viewed under the UV and IR lights in the Video Spectral Comparator 8000 for the first time. The results suggest that spectral imaging provided restoration to a good extent after heating and scraping which made the characters invisible at a relatively low depth of deformation compared to hammering. The recovery of characters with this novel technique brings a new perspective forensic marks examination literature by producing quick, successful and reliable results and facilitating reexamination by not harming the sample.

Identifiants

pubmed: 34145587
doi: 10.1111/1556-4029.14784
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2381-2386

Informations de copyright

© 2021 American Academy of Forensic Sciences.

Références

Maiden NR. Serial number restoration: firearm. In: Jamieson A, Moenssens A, editors. Wiley encyclopedia of forensic science. Hoboken, NJ: John Wiley and Sons. Inc.; 2009. p. 1-4. https://doi.org/10.1002/9780470061589.fsa347.
Wightman G, Matthew J. Restoration of stamp marks on steel components. Forensic Sci Int. 2008;180(1):32-6. https://doi.org/10.1016/j.forsciint.2008.06.017.
Rolling A. Serial number. In: Houck M, editor. Firearm and tool mark examination and identification. Waltham, MA: Academic Press; 2015. p. 137-42.
Sick. Competence guide direct part marking. 2007. https://cdn.sick.com/media/docs/0/00/100/special_information_competence_guide_direct_part_marking_de_im0058100.pdf. Accessed 25 Jan 2021.
Steen WM, Mazumder J. Laser material processing. 4th ed. London: Springer Science Business Media; 2010. p. 339. https://doi.org/10.1007/978-1-84996-062-5.
Montanini R, Quattrocchi A, Piccolo SA. Active thermography and postprocessing image enhancement for recovering of abraded and paint-covered alphanumeric identification marks. Infrared Phys Technol. 2016;78:24-30. https://doi.org/10.1016/j.infrared.2016.07.008.
Katterwe H. Recovery of serial numbers. In: Stauffer E, Bonfanti M, editors. Forensic investigation of stolen-recovered and other crime-related vehicles. Burlington, MA: Academic Press; 2006. p. 177-202.
Heard BJ. Handbook of firearms and ballistics: examining and interpreting forensic evidence. 2nd ed. Vol. 1. Hoboken, NJ: John Wiley & Sons; 2008. p. 277-8.
Tsach T, Finkelstein N, Volkov N. Analysis of a vehicle serial number alteration technique. J Forensic Identif. 2016;66(6):536-46.
Uysal S, Mercan M, Uzun L. Serial number restoration on polymer surfaces: a survey of recent literature. Forensic Chem. 2020;20:100267. https://doi.org/10.1016/j.forc.2020.100267.
Aly AA. Heat treatment of polymers: a review. Int J Mater Chem Phys. 2015;1(2):132-40.
Katterwe H. Surface damage to plastics by spices and application to forensic science (revisualisation of erased numbers using clove powder). Prakt Metallogr. 2004;41(6):286-95.
Conlan XA, Baker MJ, Krieg R, Lockyer NP, Vickerman JC, Barnett NW, et al. Insight into the swelling mechanism involved in the recovery of serial numbers erased from polymer surfaces. Surf Interface Anal. 2010;43(1-2):625-7. https://doi.org/10.1002/sia.3510.
Doty KC, Muro CK, Bueno J, Halámková L, Lednev IK. What can Raman spectroscopy do for criminalistics? J Raman Spectrosc. 2016;47(1):39-50. https://doi.org/10.1002/jrs.4826.
Parisien C, Kolhatkar G, Crispino F, Lajeunesse A, Ruediger A. Reconstruction of obliterated characters in polycarbonate through spectral imaging. Anal Chem. 2017;89(21):11648-52. https://doi.org/10.1021/acs.analchem.7b03069.
Parisien C, Kolhatkar G, Dörfler A, Crispino F, Lajeunesse A, Ruediger A. Contrast enhancement for the recovery of obliterated serial numbers in different polymers by correlated Raman imaging of strain, phonon-life time and strain-induced anisotropy. Anal Chem. 2019;91(22):14247-53. https://doi.org/10.1021/acs.analchem.9b01621.
Katterwe H. The recovery of erased numbers in polymers. J Forensic Sci Soc. 1994;34(1):11-6.
Guerra JM, Srinivasarao M, Stein RS. Photon tunneling microscopy of polymeric surfaces. Science. 1993;262(5138):1395-400. https://doi.org/10.1126/science.262.5138.1395.
Carminati R, Greffet JJ. Two-dimensional numerical simulation of the photon scanning tunneling microscope. Concept of transfer function. Opt Commun. 1995;116(4-6):316-21. https://doi.org/10.1016/0030-4018(95)91252-W.
Foster + Freeman Ltd. Products. https://www.fosterfreeman.com/product/qde-products/580-vsc8000.html. Accessed 14 Dec 2020.

Auteurs

Serdar Uysal (S)

Marks Examination Unit, Gendarmerie Forensic Department, Ankara, Turkey.
Division of Forensic Science, Institute of Science, Hacettepe University, Ankara, Turkey.

Canan Armutcu (C)

Department of Chemistry, Hacettepe University, Ankara, Turkey.

Mustafa Mercan (M)

Gendarmerie Forensic Department, Ankara, Turkey.

Lokman Uzun (L)

Division of Forensic Science, Institute of Science, Hacettepe University, Ankara, Turkey.
Department of Chemistry, Hacettepe University, Ankara, Turkey.

Classifications MeSH