Multicatalytic Transformation of (Meth)acrylic Acids: a One-Pot Approach to Biobased Poly(meth)acrylates.

(meth)acrylates biobased polymers one-pot catalysis reaction mechanisms renewable monomers

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
23 08 2021
Historique:
revised: 02 06 2021
received: 18 05 2021
pubmed: 22 6 2021
medline: 22 6 2021
entrez: 21 6 2021
Statut: ppublish

Résumé

Shifting from petrochemical feedstocks to renewable resources can address some of the environmental issues associated with petrochemical extraction and make plastics production sustainable. Therefore, there is a growing interest in selective methods for transforming abundant renewable feedstocks into monomers suitable for polymer production. Reported herein are one-pot catalytic systems, that are active, productive, and selective under mild conditions for the synthesis of copolymers from renewable materials. Each system allows for anhydride formation, alcohol acylation and/or acid esterification, as well as polymerization of the formed (meth)acrylates, providing direct access to a new library of unique poly(meth)acrylates.

Identifiants

pubmed: 34152679
doi: 10.1002/anie.202106640
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

19374-19382

Subventions

Organisme : École Polytechnique, Université Paris-Saclay
Organisme : China Scholarship Council
Organisme : Institut Universitaire de France

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Hugo Fouilloux (H)

PSL University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France.

Wei Qiang (W)

PSL University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France.

Carine Robert (C)

PSL University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France.

Vincent Placet (V)

FEMTO-ST Institute, CNRS/UFC/ENSMM/UTBM, Department of Applied Mechanics, Université de Bourgogne Franche-Comté, Besançon, France.

Christophe M Thomas (CM)

PSL University, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France.

Classifications MeSH