Identifying key mononuclear Fe species for low-temperature methane oxidation.


Journal

Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951

Informations de publication

Date de publication:
08 Jan 2021
Historique:
entrez: 24 6 2021
pubmed: 25 6 2021
medline: 25 6 2021
Statut: epublish

Résumé

The direct functionalization of methane into platform chemicals is arguably one of the holy grails in chemistry. The actual active sites for methane activation are intensively debated. By correlating a wide variety of characterization results with catalytic performance data we have been able to identify mononuclear Fe species as the active site in the Fe/ZSM-5 zeolites for the mild oxidation of methane with H

Identifiants

pubmed: 34164082
doi: 10.1039/d0sc06067d
pii: d0sc06067d
pmc: PMC8179404
doi:

Types de publication

Journal Article

Langues

eng

Pagination

3152-3160

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Tao Yu (T)

CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 China w.luo@dicp.ac.cn.
University of Chinese Academy of Sciences Beijing 100049 China.

Zhi Li (Z)

State Key Laboratory of Heavy Oil Processing, China University of Petroleum Beijing 102249 China.

Wilm Jones (W)

Department of Chemistry, University College London 20 Gordon Street London WC1H 0AJ UK andrew.beale@ucl.ac.uk.
Research Complex at Harwell (RCaH), Rutherford Appleton Laboratory Harwell, Didcot Oxon OX11 0FA UK.

Yuanshuai Liu (Y)

Inorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University Universiteitsweg 99 Utrecht 3584 CG The Netherlands B.M.Weckuysen@uu.nl.

Qian He (Q)

Department of Materials Science and Engineering, National University of Singapore Engineering Drive 1 Singapore 117575 Singapore.

Weiyu Song (W)

State Key Laboratory of Heavy Oil Processing, China University of Petroleum Beijing 102249 China.

Pengfei Du (P)

University of Chinese Academy of Sciences Beijing 100049 China.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 China.

Bing Yang (B)

Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 China.

Hongyu An (H)

Inorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University Universiteitsweg 99 Utrecht 3584 CG The Netherlands B.M.Weckuysen@uu.nl.

Daniela M Farmer (DM)

Department of Chemistry, University College London 20 Gordon Street London WC1H 0AJ UK andrew.beale@ucl.ac.uk.
Research Complex at Harwell (RCaH), Rutherford Appleton Laboratory Harwell, Didcot Oxon OX11 0FA UK.

Chengwu Qiu (C)

Department of Chemistry, University College London 20 Gordon Street London WC1H 0AJ UK andrew.beale@ucl.ac.uk.
Research Complex at Harwell (RCaH), Rutherford Appleton Laboratory Harwell, Didcot Oxon OX11 0FA UK.

Aiqin Wang (A)

CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 China w.luo@dicp.ac.cn.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Dalian 116023 China.

Bert M Weckhuysen (BM)

Inorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University Universiteitsweg 99 Utrecht 3584 CG The Netherlands B.M.Weckuysen@uu.nl.

Andrew M Beale (AM)

Department of Chemistry, University College London 20 Gordon Street London WC1H 0AJ UK andrew.beale@ucl.ac.uk.
Research Complex at Harwell (RCaH), Rutherford Appleton Laboratory Harwell, Didcot Oxon OX11 0FA UK.

Wenhao Luo (W)

CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences 457 Zhongshan Road Dalian 116023 China w.luo@dicp.ac.cn.

Classifications MeSH