Nanoscale Analysis of Historical Paintings by Means of O-PTIR Spectroscopy: The Identification of the Organic Particles in L'Arlésienne (Portrait of Madame Ginoux) by Van Gogh.
IR spectroscopy
O-PTIR
Van Gogh
historical paintings
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
11 Oct 2021
11 Oct 2021
Historique:
received:
05
05
2021
pubmed:
25
6
2021
medline:
25
6
2021
entrez:
24
6
2021
Statut:
ppublish
Résumé
Optical-photothermal infrared (O-PTIR) spectroscopy is a recently developed technique that provides spectra comparable to traditional transmission FTIR spectroscopy with nanometric spatial resolution. Hence, O-PTIR is a promising candidate for the analysis of historical paintings, as well as other cultural heritage objects, but its potential has not yet been evaluated. This work presents the first application of O-PTIR to the analysis of cultural heritage, and in particular to an extremely small fragment from Van Gogh's painting L'Arlésienne (portrait of Madame Ginoux). The striking results obtained, including the detection of geranium lake pigments as well as the complete analysis of the stratigraphy, failed with other state-of-the-art techniques, highlight the potential of this method. The integration of O-PTIR to the study of cultural heritage opens to the possibility of decreasing the amount of sample extracted, therefore contributing to the preservation of the integrity of artworks while providing a complete characterization of the materials.
Identifiants
pubmed: 34165241
doi: 10.1002/anie.202106058
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
22753-22760Subventions
Organisme : Brain-be Belspo
ID : ARTGARDEN Art Technical Research and Preservation of Historical Mixed-Media Ensembles: 'Enclosed Gardens'
Organisme : Fonds Wetenschappelijk Onderzoek
ID : High resolution Raman spectroscopy and imaging
Organisme : BOF-SEP
ID : Diagnostics for Artworks
Organisme : Synchrotron Soleil
ID : 20191722
Informations de copyright
© 2021 Wiley-VCH GmbH.
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