Integrated lipidomics and proteomics reveal cardiolipin alterations, upregulation of HADHA and long chain fatty acids in pancreatic cancer stem cells.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
24 06 2021
Historique:
received: 17 02 2021
accepted: 15 06 2021
entrez: 25 6 2021
pubmed: 26 6 2021
medline: 6 11 2021
Statut: epublish

Résumé

Pancreatic cancer stem cells (PCSCs) play a key role in the aggressiveness of pancreatic ductal adenocarcinomas (PDAC); however, little is known about their signaling and metabolic pathways. Here we show that PCSCs have specific and common proteome and lipidome modulations. PCSCs displayed downregulation of lactate dehydrogenase A chain, and upregulation of trifunctional enzyme subunit alpha. The upregulated proteins of PCSCs are mainly involved in fatty acid (FA) elongation and biosynthesis of unsaturated FAs. Accordingly, lipidomics reveals an increase in long and very long-chain unsaturated FAs, which are products of fatty acid elongase-5 predicted as a key gene. Moreover, lipidomics showed the induction in PCSCs of molecular species of cardiolipin with mixed incorporation of 16:0, 18:1, and 18:2 acyl chains. Our data indicate a crucial role of FA elongation and alteration in cardiolipin acyl chain composition in PCSCs, representing attractive therapeutic targets in PDAC.

Identifiants

pubmed: 34168259
doi: 10.1038/s41598-021-92752-5
pii: 10.1038/s41598-021-92752-5
pmc: PMC8225828
doi:

Substances chimiques

Cardiolipins 0
HADHA protein, human EC 1.1.1.211
Mitochondrial Trifunctional Protein, alpha Subunit EC 1.1.1.211

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

13297

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Auteurs

Claudia Di Carlo (C)

Mass Spectrometry and Proteomics Lab, Department of Biotechnology, University of Verona, Strada le Grazie 15, 37134, Verona, Italy.

Bebiana C Sousa (BC)

Lipidomics Facility, Babraham Research Campus, Babraham Institute, Cambridge, CB22 3AT, UK.

Marcello Manfredi (M)

Department of Sciences and Technological Innovation, University of Eastern Piedmont, 15121, Alessandria, Italy.

Jessica Brandi (J)

Mass Spectrometry and Proteomics Lab, Department of Biotechnology, University of Verona, Strada le Grazie 15, 37134, Verona, Italy.

Elisa Dalla Pozza (E)

Department of Neurosciences, Biomedicine and Movement Sciences, University of Verona, 37134, Verona, Italy.

Emilio Marengo (E)

Department of Sciences and Technological Innovation, University of Eastern Piedmont, 15121, Alessandria, Italy.

Marta Palmieri (M)

Department of Neurosciences, Biomedicine and Movement Sciences, University of Verona, 37134, Verona, Italy.

Ilaria Dando (I)

Department of Neurosciences, Biomedicine and Movement Sciences, University of Verona, 37134, Verona, Italy.

Michael J O Wakelam (MJO)

Lipidomics Facility, Babraham Research Campus, Babraham Institute, Cambridge, CB22 3AT, UK.

Andrea F Lopez-Clavijo (AF)

Lipidomics Facility, Babraham Research Campus, Babraham Institute, Cambridge, CB22 3AT, UK.

Daniela Cecconi (D)

Mass Spectrometry and Proteomics Lab, Department of Biotechnology, University of Verona, Strada le Grazie 15, 37134, Verona, Italy. daniela.cecconi@univr.it.

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Classifications MeSH