Chemical Oxidative Polymerization of Methylene Blue: Reaction Mechanism and Aspects of Chain Structure.
electrical conductivity of polymers
methylene blue
oxidative polymerization
paramagnetic polymers
polymethylene blue
Journal
Polymers
ISSN: 2073-4360
Titre abrégé: Polymers (Basel)
Pays: Switzerland
ID NLM: 101545357
Informations de publication
Date de publication:
30 Jun 2021
30 Jun 2021
Historique:
received:
14
06
2021
revised:
25
06
2021
accepted:
28
06
2021
entrez:
2
7
2021
pubmed:
3
7
2021
medline:
3
7
2021
Statut:
epublish
Résumé
The kinetic regularities of the initial stage of chemical oxidative polymerization of methylene blue under the action of ammonium peroxodisulfate in an aqueous medium have been established by the method of potentiometry. It was shown that the methylene blue polymerization mechanism includes the stages of chain initiation and growth. It was found that the rate of the initial stage of the reaction obeys the kinetic equation of the first order with the activation energy 49 kJ × mol
Identifiants
pubmed: 34209367
pii: polym13132188
doi: 10.3390/polym13132188
pmc: PMC8271652
pii:
doi:
Types de publication
Journal Article
Langues
eng
Subventions
Organisme : D. Mendeleev University of Chemical Technology of Russia
ID : K-2020-001
Déclaration de conflit d'intérêts
The authors declare no conflict of interest.
Références
Analyst. 2013 Oct 7;138(19):5811-8
pubmed: 23897002
ACS Omega. 2018 Jul 02;3(7):7196-7203
pubmed: 31458882
Mater Sci Eng C Mater Biol Appl. 2017 Apr 1;73:552-561
pubmed: 28183644
ACS Omega. 2021 Apr 02;6(14):9528-9536
pubmed: 33869933
J Anal Methods Chem. 2014;2014:984314
pubmed: 25436174
An Acad Bras Cienc. 2017 Jul-Sep;89(3):1381-1389
pubmed: 28813104
Sci Rep. 2020 Aug 7;10(1):13412
pubmed: 32770071
Materials (Basel). 2010 Dec 02;3(12):5130-5142
pubmed: 28883373
J Phys Chem A. 2015 Apr 2;119(13):3233-43
pubmed: 25742158