Tuning the Magnetic Anisotropy of Lanthanides on a Metal Substrate by Metal-Organic Coordination.
X-ray magnetic circular dichroism
lanthanides
magnetic anisotropy
metal-organic networks
single atom magnetism
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
Sep 2021
Sep 2021
Historique:
revised:
25
06
2021
received:
11
05
2021
pubmed:
20
7
2021
medline:
20
7
2021
entrez:
19
7
2021
Statut:
ppublish
Résumé
Taming the magnetic anisotropy of lanthanides through coordination environments is crucial to take advantage of the lanthanides properties in thermally robust nanomaterials. In this work, the electronic and magnetic properties of Dy-carboxylate metal-organic networks on Cu(111) based on an eightfold coordination between Dy and ditopic linkers are inspected. This surface science study based on scanning probe microscopy and X-ray magnetic circular dichroism, complemented with density functional theory and multiplet calculations, reveals that the magnetic anisotropy landscape of the system is complex. Surface-supported metal-organic coordination is able to induce a change in the orientation of the easy magnetization axis of the Dy coordinative centers as compared to isolated Dy atoms and Dy clusters, and significantly increases the magnetic anisotropy. Surprisingly, Dy atoms coordinated in the metallosupramolecular networks display a nearly in-plane easy magnetization axis despite the out-of-plane symmetry axis of the coordinative molecular lattice. Multiplet calculations highlight the decisive role of the metal-organic coordination, revealing that the tilted orientation is the result of a very delicate balance between the interaction of Dy with O atoms and the precise geometry of the crystal field. This study opens new avenues to tailor the magnetic anisotropy and magnetic moments of lanthanide elements on surfaces.
Identifiants
pubmed: 34279062
doi: 10.1002/smll.202102753
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2102753Subventions
Organisme : BOREAS
ID : 2015091454
Organisme : Marie Sklodowska-Curie Actions
ID : 894924
Organisme : European Union's Horizon 2020 research and innovation programme
Organisme : Spanish Ministerio de Economía, Industria y Competitividad
ID : FIS2016-78591-C3-1-R
Organisme : Spanish Ministerio de Economía, Industria y Competitividad
ID : RTI2018-097895-B-C42
Organisme : Spanish Ministerio de Economía, Industria y Competitividad
ID : MAT2016-78293-C6-2-R
Organisme : Spanish Ministerio de Economía, Industria y Competitividad
ID : MAT2017-85089-C2-1-R
Organisme : Spanish Ministerio de Economía, Industria y Competitividad
ID : PID2019-107338RB-C65
Organisme : Comunidad de Madrid
ID : S2013/MIT-2850
Organisme : Comunidad de Madrid
ID : P2018/NMT4321
Organisme : Comunidad de Madrid
ID : S2018/NMT-4367
Organisme : Interreg
ID : EFA 194/16 TNSI
Organisme : Interreg
ID : SEV-2016-0686
Organisme : Interreg
ID : SEV-2017-0706
Organisme : Ministerio de Economía, Industria y Competitividad, Gobierno de España
ID : SEV-2017-0706
Organisme : H2020 Marie Skłodowska-Curie Actions
ID : 894924
Organisme : H2020 European Research Council
ID : 766555
Organisme : European Research Council
ID : 766555
Pays : International
Informations de copyright
© 2021 The Authors. Small published by Wiley-VCH GmbH.
Références
S. V. Eliseeva, J. -C. G. Bünzli, New J. Chem. 2011, 35, 1165.
J. -C. G. Bünzli, J. Coord. Chem. 2014, 67, 3706.
D. Écija, J. I. Urgel, A. P. Seitsonen, W. Auwärter, J. V. Barth, Acc. Chem. Res. 2018, 51, 365.
F. Donati, S. Rusponi, S. Stepanow, C. Wäckerlin, A. Singha, L. Persichetti, R. Baltic, K. Diller, F. Patthey, E. Fernandes, J. Dreiser, Ž. Šljivančanin, K. Kummer, C. Nistor, P. Gambardella, H. Brune, Science 2016, 352, 318.
F. D. Natterer, K. Yang, W. Paul, P. Willke, T. Choi, T. Greber, A. J. Heinrich, C. P. Lutz, Nature 2017, 543, 226.
F. Donati, A. Singha, S. Stepanow, C. Wäckerlin, J. Dreiser, P. Gambardella, S. Rusponi, H. Brune, Phys. Rev. Lett. 2014, 113, 237201.
J. D. Rinehart, J. R. Long, Chem. Sci. 2011, 2, 2078.
T. Schuh, T. Miyamachi, S. Gerstl, M. Geilhufe, M. Hoffmann, S. Ostanin, W. Hergert, A. Ernst, W. Wulfhekel, Nano Lett. 2012, 12, 4805.
S. T. Liddle, J. van Slageren, Chem. Soc. Rev. 2015, 44, 6655.
P. Stoll, M. Bernien, D. Rolf, F. Nickel, Q. Xu, C. Hartmann, T. R. Umbach, J. Kopprasch, J. N. Ladenthin, E. Schierle, E. Weschke, C. Czekelius, W. Kuch, K. J. Franke, Phys. Rev. B 2016, 94, 224426.
J. V. Barth, Annu. Rev. Phys. Chem. 2007, 58, 375.
L. Dong, Z. Gao, N. Lin, Prog. Surf. Sci. 2016, 91, 101.
B. Cirera, L. Dordevic, R. Otero, J. M. Gallego, D. Bonifazi, R. Miranda, D. Ecija, Chem. Commun. 2016, 52, 11227.
J. I. Urgel, B. Cirera, Y. Wang, W. Auwärter, R. Otero, J. M. Gallego, M. Alcamí, S. Klyatskaya, M. Ruben, F. Martín, R. Miranda, D. Ecija, J. V. Barth, Small 2015, 11, 6358.
J. I. Urgel, D. Ecija, W. Auwärter, D. Stassen, D. Bonifazi, J. V. Barth, Angew. Chem., Int. Ed. 2015, 54, 6163.
D. Écija, J. I. Urgel, A. C. Papageorgiou, S. Joshi, W. Auwärter, A. P. Seitsonen, S. Klyatskaya, M. Ruben, S. Fischer, S. Vijayaraghavan, J. Reichert, J. V. Barth, Proc. Natl. Acad. Sci. U. S. A. 2013, 110, 6678.
J. I. Urgel, D. Écija, G. Lyu, R. Zhang, C. -A. Palma, W. Auwärter, N. Lin, J. V. Barth, Nat. Chem. 2016, 8, 657.
G. Lyu, Q. Zhang, J. I. Urgel, G. Kuang, W. Auwärter, D. Ecija, J. V. Barth, N. Lin, Chem. Commun. 2016, 52, 1618.
J. -C. G. Bünzli, Acc. Chem. Res. 2006, 39, 53.
N. Ishikawa, Y. Mizuno, S. Takamatsu, T. Ishikawa, S. Koshihara, Inorg. Chem. 2008, 47, 10217.
A. Singha, R. Baltic, F. Donati, C. Wäckerlin, J. Dreiser, L. Persichetti, S. Stepanow, P. Gambardella, S. Rusponi, H. Brune, Phys. Rev. B 2017, 96, 224418.
D. Casanova, M. Llunell, P. Alemany, S. Alvarez, Chem. - Eur. J. 2005, 11, 1479.
A. Kumar, K. Banerjee, A. S. Foster, P. Liljeroth, Nano Lett. 2018, 18, 5596.
J. Li, L. Solianyk, N. Schmidt, B. Baker, S. Gottardi, J. C. M. Lopez, M. Enache, L. Monjas, R. van der Vlag, R. W. A. Havenith, A. K. H. Hirsch, M. Stöhr, J. Phys. Chem. C 2019, 123, 12730.
R. Baltic, F. Donati, A. Singha, C. Wäckerlin, J. Dreiser, B. Delley, M. Pivetta, S. Rusponi, H. Brune, Phys. Rev. B 2018, 98, 024412.
M. N. Bochkarev, Coord. Chem. Rev. 2004, 248, 835.
M. Studniarek, C. Wäckerlin, A. Singha, R. Baltic, K. Diller, F. Donati, S. Rusponi, H. Brune, Y. Lan, S. Klyatskaya, M. Ruben, A. P. Seitsonen, J. Dreiser, Adv. Sci. 2019, 6, 1901736.
H. Wang, K. Wang, J. Tao, J. Jiang, Chem. Commun. 2012, 48, 2973.
A. Singha, F. Donati, C. Wäckerlin, R. Baltic, J. Dreiser, M. Pivetta, S. Rusponi, H. Brune, Nano Lett. 2016, 16, 3475.
B. T. Thole, P. Carra, F. Sette, G. van der Laan, Phys. Rev. Lett. 1992, 68, 1943.
P. Carra, B. T. Thole, M. Altarelli, X. Wang, Phys. Rev. Lett. 1993, 70, 694.
M. Murugesu, Nat. Chem. 2012, 4, 347.
C. Wäckerlin, F. Donati, A. Singha, R. Baltic, S. Rusponi, K. Diller, F. Patthey, M. Pivetta, Y. Lan, S. Klyatskaya, M. Ruben, H. Brune, J. Dreiser, Adv. Mater. 2016, 28, 5195.
G. Cucinotta, M. Perfetti, J. Luzon, M. Etienne, P. -E. Car, A. Caneschi, G. Calvez, K. Bernot, R. Sessoli, Angew. Chem., Int. Ed. 2012, 51, 1606.
P. Gambardella, S. Rusponi, M. Veronese, S. S. Dhesi, C. Grazioli, A. Dallmeyer, I. Cabria, R. Zeller, P. H. Dederichs, K. Kern, C. Carbone, H. Brune, Science 2003, 300, 1130.
A. Uldry, F. Vernay, B. Delley, Phys. Rev. B 2012, 85, 125133.
R. Baltic, M. Pivetta, F. Donati, C. Wäckerlin, A. Singha, J. Dreiser, S. Rusponi, H. Brune, Nano Lett. 2016, 16, 7610.
Y. -S. Ding, K. -X. Yu, D. Reta, F. Ortu, R. E. P. Winpenny, Y. -Z. Zheng, N. F. Chilton, Nat. Commun. 2018, 9, 3134.
D. Gatteschi, R. Sessoli, Angew. Chem., Int. Ed. 2003, 42, 268.
G. Huang, G. Fernandez-Garcia, I. Badiane, M. Camarra, S. Freslon, O. Guillou, C. Daiguebonne, F. Totti, O. Cador, T. Guizouarn, B. L. Guennic, K. Bernot, Chem. - Eur. J. 2018, 24, 6983.
F. D. Natterer, F. Donati, F. Patthey, H. Brune, Phys. Rev. Lett. 2018, 121, 027201.
D. Coffey, C. de la Fuente, M. Ciria, D. Serrate, S. Loth, J. I. Arnaudas, Phys. Chem. Chem. Phys. 2020, 22, 196.
D. Moreno, B. Cirera, S. O. Parreiras, J. I. Urgel, N. Giménez-Agulló, K. Lauwaet, J. M. Gallego, J. R. Galán-Mascarós, J. I. Martínez, P. Ballester, R. Miranda, D. Écija, Chem. Commun. 2021, 57, 1380.
M. Mannini, F. Bertani, C. Tudisco, L. Malavolti, L. Poggini, K. Misztal, D. Menozzi, A. Motta, E. Otero, P. Ohresser, P. Sainctavit, G. G. Condorelli, E. Dalcanale, R. Sessoli, Nat. Commun. 2014, 5, 4582.
N. A. Anderson, Q. Zhang, M. Hupalo, R. A. Rosenberg, J. W. Freeland, M. C. Tringides, D. Vaknin, J. Magn. Magn. Mater. 2017, 435, 212.
Y. Teramura, A. Tanaka, B. T. Thole, T. Jo, J. Phys. Soc. Jpn. 1996, 65, 3056.
P. Giannozzi, S. Baroni, N. Bonini, M. Calandra, R. Car, C. Cavazzoni, D. Ceresoli, G. L. Chiarotti, M. Cococcioni, I. Dabo, A. Dal Corso, S. de Gironcoli, S. Fabris, G. Fratesi, R. Gebauer, U. Gerstmann, C. Gougoussis, A. Kokalj, M. Lazzeri, L. Martin-Samos, N. Marzari, F. Mauri, R. Mazzarello, S. Paolini, A. Pasquarello, L. Paulatto, C. Sbraccia, S. Scandolo, G. Sclauzero, A. P. Seitsonen, A. Smogunov, P. Umari, R. M. Wentzcovitch, J. Phys.: Condens. Matter 2009, 21, 395502.
L. A. Constantin, J. P. Perdew, J. M. Pitarke, Phys. Rev. B 2009, 79, 075126.
J. P. Perdew, A. Ruzsinszky, G. I. Csonka, O. A. Vydrov, G. E. Scuseria, L. A. Constantin, X. Zhou, K. Burke, Phys. Rev. Lett. 2008, 100, 136406.
G. Kresse, J. Joubert, Phys. Rev. B 1999, 59, 1758.
J. D. Pack, H. J. Monkhorst, Phys. Rev. B 1977, 16, 1748.
S. Grimme, J. Antony, S. Ehrlich, H. Krieg, J. Chem. Phys. 2010, 132, 154104.
M. Methfessel, A. T. Paxton, Phys. Rev. B 1989, 40, 3616.