X-ray studies bridge the molecular and macro length scales during the emergence of CoO assemblies.
Journal
Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555
Informations de publication
Date de publication:
20 Jul 2021
20 Jul 2021
Historique:
received:
27
01
2021
accepted:
24
06
2021
entrez:
21
7
2021
pubmed:
22
7
2021
medline:
22
7
2021
Statut:
epublish
Résumé
The key to fabricating complex, hierarchical materials is the control of chemical reactions at various length scales. To this end, the classical model of nucleation and growth fails to provide sufficient information. Here, we illustrate how modern X-ray spectroscopic and scattering in situ studies bridge the molecular- and macro- length scales for assemblies of polyhedrally shaped CoO nanocrystals. Utilizing high energy-resolution fluorescence-detected X-ray absorption spectroscopy, we directly access the molecular level of the nanomaterial synthesis. We reveal that initially Co(acac)
Identifiants
pubmed: 34285227
doi: 10.1038/s41467-021-24557-z
pii: 10.1038/s41467-021-24557-z
pmc: PMC8292528
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4429Subventions
Organisme : EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council)
ID : 818941
Organisme : EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council)
ID : 818941
Organisme : Deutsche Forschungsgemeinschaft (German Research Foundation)
ID : 201269156-SFB1032
Organisme : Deutsche Forschungsgemeinschaft (German Research Foundation)
ID : 390715994-EXC2056
Organisme : Deutsche Forschungsgemeinschaft (German Research Foundation)
ID : 201269156-SFB1032
Organisme : Deutsche Forschungsgemeinschaft (German Research Foundation)
ID : 390715994-EXC2056
Organisme : Bundesministerium für Bildung und Forschung (Federal Ministry of Education and Research)
ID : 05K19WMA
Organisme : Bundesministerium für Bildung und Forschung (Federal Ministry of Education and Research)
ID : 05K19WMA
Informations de copyright
© 2021. The Author(s).
Références
Acc Chem Res. 2007 Sep;40(9):793-800
pubmed: 17461544
Nat Commun. 2017 Oct 3;8(1):768
pubmed: 28974672
Nanoscale. 2020 Jul 2;12(25):13276-13296
pubmed: 32567636
Acta Crystallogr C. 2000 Jun;56 (Pt 6):649-50
pubmed: 10902006
IUCrJ. 2014 Apr 14;1(Pt 3):165-71
pubmed: 25075335
J Chem Theory Comput. 2009 May 12;5(5):1237-44
pubmed: 26609714
Small. 2011 Feb 7;7(3):377-87
pubmed: 21294267
Inorg Chem. 2010 Sep 20;49(18):8430-4
pubmed: 20795642
Nature. 2000 Mar 2;404(6773):59-61
pubmed: 10716439
ACS Nano. 2009 Feb 24;3(2):467-77
pubmed: 19236087
Sci Rep. 2017 Jun 5;7(1):2802
pubmed: 28584236
Acta Crystallogr C. 2007 Jul;63(Pt 7):m283-8
pubmed: 17609546
J Am Chem Soc. 2012 Apr 18;134(15):6785-92
pubmed: 22420861
Angew Chem Int Ed Engl. 2012 Nov 19;51(47):11770-3
pubmed: 23073995
Angew Chem Int Ed Engl. 2011 Mar 14;50(12):2841-4
pubmed: 21387501
Rev Sci Instrum. 2016 Feb;87(2):025103
pubmed: 26931887
Proc Natl Acad Sci U S A. 2015 Dec 29;112(52):15803-8
pubmed: 26668362
J Appl Crystallogr. 2015 Mar 24;48(Pt 2):510-519
pubmed: 25844080
J Am Chem Soc. 2019 Mar 20;141(11):4490-4504
pubmed: 30753066
Nano Lett. 2011 Jun 8;11(6):2560-6
pubmed: 21553924
Angew Chem Int Ed Engl. 2019 Dec 2;58(49):17558-17562
pubmed: 31621992
Science. 2000 Feb 25;287(5457):1471-3
pubmed: 10688792
J Magn Magn Mater. 2009 May;321(10):1529-1532
pubmed: 20160860
J Am Chem Soc. 2015 Apr 1;137(12):4223-9
pubmed: 25759959
Sci Rep. 2016 Jun 03;6:27081
pubmed: 27255562
Science. 2010 Jul 30;329(5991):550-3
pubmed: 20671184
Nano Lett. 2018 Jun 13;18(6):3675-3681
pubmed: 29781269
Science. 2009 Jun 12;324(5933):1417-20
pubmed: 19520953
Nanoscale. 2012 Mar 21;4(6):1982-95
pubmed: 22159429
J Synchrotron Radiat. 2001 Mar 1;8(Pt 2):599-601
pubmed: 11512864
J Synchrotron Radiat. 2012 Jul;19(Pt 4):647-53
pubmed: 22713902
J Synchrotron Radiat. 2016 May;23(Pt 3):836-41
pubmed: 27140166
Nat Nanotechnol. 2014 Jan;9(1):69-73
pubmed: 24336404
J Am Chem Soc. 2002 Sep 25;124(38):11480-5
pubmed: 12236762
J Synchrotron Radiat. 2005 Jul;12(Pt 4):537-41
pubmed: 15968136
Chem Rev. 2010 Jan;110(1):389-458
pubmed: 19958036
Phys Chem Chem Phys. 2010 Jun 7;12(21):5503-13
pubmed: 20445945
Nanoscale. 2020 Aug 13;12(31):16420-16426
pubmed: 32744559
Science. 2015 Jan 16;347(6219):292-4
pubmed: 25593188
Nanoscale. 2014 Dec 21;6(24):14716-23
pubmed: 25317831
J Am Chem Soc. 2019 Oct 16;141(41):16312-16322
pubmed: 31542922
J Am Chem Soc. 2010 Mar 3;132(8):2555-7
pubmed: 20121279
Nat Commun. 2019 Sep 17;10(1):4228
pubmed: 31530817
Langmuir. 2010 Sep 21;26(18):14943-50
pubmed: 20804155
ACS Nano. 2011 Mar 22;5(3):2182-90
pubmed: 21309559
ACS Appl Mater Interfaces. 2017 May 24;9(20):17195-17200
pubmed: 28471161
Nano Lett. 2014 Mar 12;14(3):1433-8
pubmed: 24499132
Science. 2015 Jul 31;349(6247):aaa6760
pubmed: 26228157
J Phys Condens Matter. 2009 Mar 11;21(10):104207
pubmed: 21817427
J Am Chem Soc. 2019 Jul 3;141(26):10120-10136
pubmed: 31173682
ACS Nano. 2020 May 26;14(5):5337-5347
pubmed: 32338498
J Phys Condens Matter. 2007 Aug 22;19(33):335219
pubmed: 21694142