Tailored Design of Electrochemically Degradable Anthraquinone Functionality toward Organic Cathodes.

In efforts to design organic cathode materials for rechargeable batteries, a fundamental understanding of the redox properties of diverse non-carbon-based functionalities incorporated into 9,10-anthraquinone is lacking despite their potential impact. Herein, a preliminary investigation of the potential of anthraquinones with halogenated nitrogen-based functionalities reveals that the Li-triggered structural collapse observed in the early stage of discharging can be ascribed to the preference toward the strong Lewis acid-base interaction of N-Li-X (X = F or Cl) over the repulsive interaction of the electron-rich N-X bond. A further study of three solutions (