Strong isotope effect in the VUV photodissociation of HOD: A possible origin of D/H isotope heterogeneity in the solar nebula.
Journal
Science advances
ISSN: 2375-2548
Titre abrégé: Sci Adv
Pays: United States
ID NLM: 101653440
Informations de publication
Date de publication:
Jul 2021
Jul 2021
Historique:
received:
28
01
2021
accepted:
04
06
2021
entrez:
22
7
2021
pubmed:
23
7
2021
medline:
23
7
2021
Statut:
epublish
Résumé
The deuterium versus hydrogen (D/H) isotopic ratios are important to understand the source of water on Earth and other terrestrial planets. However, the determinations of D/H ratios suggest a hydrogen isotopic diversity in the planetary objects of the solar system. Photochemistry has been suggested as one source of this isotope heterogeneity. Here, we have revealed the photodissociation features of the water isotopologue (HOD) at λ = 120.8 to 121.7 nm. The results show different quantum state populations of OH and OD fragments from HOD photodissociation, suggesting strong isotope effect. The branching ratios of H + OD and D + OH channels display large isotopic fractionation, with ratios of 0.70 ± 0.10 at 121.08 nm and 0.49 ± 0.10 at 121.6 nm. Because water is abundant in the solar nebula, photodissociation of HOD should be an alternative source of the D/H isotope heterogeneity. This isotope effect must be considered in the photochemical models.
Identifiants
pubmed: 34290097
pii: 7/30/eabg7775
doi: 10.1126/sciadv.abg7775
pmc: PMC8294749
pii:
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Informations de copyright
Copyright © 2021 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).
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