Avoiding the Center-Symmetry Trap: Programmed Assembly of Dipolar Precursors into Porous, Crystalline Molecular Thin Films.
electrostatic design
metal-organic frameworks
second-harmonic generation
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Sep 2021
Sep 2021
Historique:
revised:
17
06
2021
received:
29
04
2021
pubmed:
23
7
2021
medline:
23
7
2021
entrez:
22
7
2021
Statut:
ppublish
Résumé
Liquid-phase, quasi-epitaxial growth is used to stack asymmetric, dipolar organic compounds on inorganic substrates, permitting porous, crystalline molecular materials that lack inversion symmetry. This allows material fabrication with built-in electric fields. A new programmed assembly strategy based on metal-organic frameworks (MOFs) is described that facilitates crystalline, noncentrosymmetric space groups for achiral compounds. Electric fields are integrated into crystalline, porous thin films with an orientation normal to the substrate. Changes in electrostatic potential are detected via core-level shifts of marker atoms on the MOF thin films and agree with theoretical results. The integration of built-in electric fields into organic, crystalline, and porous materials creates possibilities for band structure engineering to control the alignment of electronic levels in organic molecules. Built-in electric fields may also be used to tune the transfer of charges from donors loaded via programmed assembly into MOF pores. Applications include organic electronics, photonics, and nonlinear optics, since the absence of inversion symmetry results in a clear second-harmonic generation signal.
Identifiants
pubmed: 34291511
doi: 10.1002/adma.202103287
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2103287Subventions
Organisme : Deutsche Forschungsgemeinschaft (DFG
Organisme : German Research Foundation) under Germany's Excellence Strategy
ID : 2082/1
Organisme : German Research Foundation) under Germany's Excellence Strategy
ID : 390761711
Organisme : Graz University of Technology lead project (LP-03)
Organisme : State of Baden-Württemberg through bwHPC and the German Research Foundation (DFG)
ID : INST 40/575-1 FUGG
Organisme : State of Baden-Württemberg through bwHPC and the German Research Foundation (DFG)
ID : INST 35/1134-1 FUGG
Organisme : Volkswagen Foundation
Informations de copyright
© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.
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