Immobilization of molybdenum by alternative cementitious binders and synthetic C-S-H: An experimental and numerical study.

Excavation operations during construction produce millions of tons of soil sometimes with high leachable molybdenum (Mo) contents, that can lead to risks for both human health and the environment. It is therefore necessary to immobilize the Mo in excavated soils to reduce pollution and lower the costs of soil disposal. This paper studies the immobilization of Mo by three cementitious binders. To this end, one Ordinary Portland cement (OPC), one binder composed of 90% ground granulated blast furnace slag (GGBS) and 10% OPC, and one supersulfated GGBS binder were spiked with sodium molybdate at six different Mo concentrations from 0.005 wt% to 10 wt% before curing. In addition, to gain mechanistic insights, the capacity of synthetic calcium silicate hydrates (C-S-H) to immobilize Mo was studied. This study was completed by thermodynamic modeling to predict the immobilization of Mo at low Mo concentrations (<0.005 wt%). Paste leaching tests results showed that more than 74% of the initial Mo spike was immobilized by the three binders. The supersulfated GGBS binder consistently showed the highest retention levels (92.0 to 99.7%). The precipitation of powellite (CaMoO

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Declaration of competing interest The authors declare no conflict of interest.