Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilide Ligands.

cooperative effects ferrates metallation sodium bimetallic compounds

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
02 Nov 2021
Historique:
received: 28 06 2021
pubmed: 30 7 2021
medline: 30 7 2021
entrez: 29 7 2021
Statut: ppublish

Résumé

Alkali-metal ferrates containing amide groups have emerged as regioselective bases capable of promoting Fe-H exchanges of aromatic substrates. Advancing this area of heterobimetallic chemistry, a new series of sodium ferrates is introduced incorporating the bulky arylsilyl amido ligand N(SiMe

Identifiants

pubmed: 34324749
doi: 10.1002/chem.202102328
pmc: PMC8596604
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

15180-15186

Subventions

Organisme : schweizerischer nationalfonds zur förderung der wissenschaftlichen forschung
ID : 188573

Informations de copyright

© 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

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Auteurs

Lewis C H Maddock (LCH)

Department für Chemie, Biochemie und Pharmazie, Universität Bern, Freiestrasse 3, 3012, Bern, Switzerland.

Rebekka Morton (R)

WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral St, Glasgow, G1 1XL, UK.

Alan R Kennedy (AR)

WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral St, Glasgow, G1 1XL, UK.

Eva Hevia (E)

Department für Chemie, Biochemie und Pharmazie, Universität Bern, Freiestrasse 3, 3012, Bern, Switzerland.

Classifications MeSH