Ultrastrong and Ductile Soft Magnetic High-Entropy Alloys via Coherent Ordered Nanoprecipitates.

coherent ordered precipitation high-entropy alloys mechanical properties soft magnetic properties

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Sep 2021
Historique:
revised: 05 06 2021
received: 18 03 2021
pubmed: 3 8 2021
medline: 3 8 2021
entrez: 2 8 2021
Statut: ppublish

Résumé

The lack of strength and damage tolerance can limit the applications of conventional soft magnetic materials (SMMs), particularly in mechanically loaded functional devices. Therefore, strengthening and toughening of SMMs is critically important. However, conventional strengthening concepts usually significantly deteriorate soft magnetic properties, due to Bloch wall interactions with the defects used for hardening. Here a novel concept to overcome this dilemma is proposed, by developing bulk SMMs with excellent mechanical and attractive soft magnetic properties through coherent and ordered nanoprecipitates (<15 nm) dispersed homogeneously within a face-centered cubic matrix of a non-equiatomic CoFeNiTaAl high-entropy alloy (HEA). Compared to the alloy in precipitate-free state, the alloy variant with a large volume fraction (>42%) of nanoprecipitates achieves significantly enhanced strength (≈1526 MPa) at good ductility (≈15%), while the coercivity is only marginally increased (<10.7 Oe). The ordered nanoprecipitates and the resulting dynamic microband refinement in the matrix significantly strengthen the HEAs, while full coherency between the nanoprecipitates and the matrix leads at the same time to the desired insignificant pinning of the magnetic domain walls. The findings provide guidance for developing new high-performance materials with an excellent combination of mechanical and soft magnetic properties as needed for the electrification of transport and industry.

Identifiants

pubmed: 34337799
doi: 10.1002/adma.202102139
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2102139

Informations de copyright

© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.

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Auteurs

Liuliu Han (L)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Ziyuan Rao (Z)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Isnaldi R Souza Filho (IR)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Fernando Maccari (F)

Functional Materials, Materials Science, Technical University of Darmstadt, 64287, Darmstadt, Germany.

Ye Wei (Y)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Ge Wu (G)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Ali Ahmadian (A)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Xuyang Zhou (X)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Oliver Gutfleisch (O)

Functional Materials, Materials Science, Technical University of Darmstadt, 64287, Darmstadt, Germany.

Dirk Ponge (D)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Dierk Raabe (D)

Max-Planck-Institut für Eisenforschung, Max-Planck-Straße 1, 40237, Düsseldorf, Germany.

Zhiming Li (Z)

School of Materials Science and Engineering, Central South University, Changsha, 410083, China.
Key Laboratory of Nonferrous Metal Materials Science and Engineering, Ministry of Education, Central South University, Changsha, 410083, China.

Classifications MeSH