Metavalent Bonding in Crystalline Solids: How Does It Collapse?
atom probe tomography
bond breaking
materials by design
metavalent bonding
phase-change materials
property maps
thermoelectrics
topological insulators
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Oct 2021
Oct 2021
Historique:
revised:
26
05
2021
received:
26
03
2021
pubmed:
7
8
2021
medline:
7
8
2021
entrez:
6
8
2021
Statut:
ppublish
Résumé
The chemical bond is one of the most powerful, yet much debated concepts in chemistry, explaining property trends in solids. Recently, a novel type of chemical bonding was identified in several higher chalcogenides, characterized by a unique property portfolio, unconventional bond breaking, and sharing of about one electron between adjacent atoms. This metavalent bond is a fundamental type of bonding in solids, besides covalent, ionic, and metallic bonding, raising the pertinent question as to whether there is a well-defined transition between metavalent and covalent bonds. Here, three different pseudo-binary lines, namely, GeTe
Identifiants
pubmed: 34355435
doi: 10.1002/adma.202102356
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2102356Subventions
Organisme : ERC
ID : 340698
Organisme : ERS Start-Up
ID : StUpPD_324-18
Organisme : FRS-FNRS
ID : ABIGLO J.0154.21
Organisme : CÉCI
ID : 2.5020.11
Organisme : Fédération Wallonie-Bruxelles
ID : 1117545
Informations de copyright
© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.
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