Natural thymol-based ternary deep eutectic solvents: Application in air-bubble assisted-dispersive liquid-liquid microextraction for the analysis of tetracyclines in water.
Chromatography, High Pressure Liquid
Deep Eutectic Solvents
/ chemistry
Drug Residues
/ analysis
Hydrophobic and Hydrophilic Interactions
Limit of Detection
Linear Models
Liquid Phase Microextraction
/ methods
Reproducibility of Results
Tetracyclines
/ analysis
Thymol
/ chemistry
Water Pollutants, Chemical
/ analysis
air bubble assisted microextraction
environmental waters
ternary deep eutectic solvents
tetracyclines
Journal
Journal of separation science
ISSN: 1615-9314
Titre abrégé: J Sep Sci
Pays: Germany
ID NLM: 101088554
Informations de publication
Date de publication:
Oct 2021
Oct 2021
Historique:
revised:
31
07
2021
received:
23
06
2021
accepted:
03
08
2021
pubmed:
7
8
2021
medline:
28
1
2022
entrez:
6
8
2021
Statut:
ppublish
Résumé
Four new thymol-based ternary deep eutectic solvents were prepared and evaluated as the extractive phase in air-bubbles assisted dispersive liquid-liquid microextraction for extraction of tetracycline, doxycycline, and oxytetracycline from the water before high-performance liquid chromatography. The maximum extraction efficiencies were obtained using 400 μL of [choline chloride]:[thymol]:[nonanoic acid] in the molar ratio of 1:2:2 at pH = 5. The solvent was characterized by FTIR and NMR spectroscopy. The hydrophobicity of the deep eutectic solvent and its effect on the pH of water samples after mixing was also studied. Besides, the extraction efficiency of the ternary deep eutectic solvent was compared with that of two binary thymol-based deep eutectic solvents, including [choline chloride]:[thymol] and [thymol]:[nonanoic acid] at the same conditions. Under optimal conditions, limits of detection and quantification were 1.2-8.0 and 3.8-26.6 μg/L, respectively. The linear ranges were 18.2-500 μg/L for oxytetracycline, 26.6-500 μg/L for tetracycline, and 3.8-500 μg/L for doxycycline with the determination coefficients > 0.9912. Intra- and inter-day relative standard deviations were 1.2-3.8 and 7.7-11.2%, respectively. The developed method was applied to the analysis of tetracyclines in unspiked and spiked environmental water samples, and the obtained recoveries were 74.5-95.4% with relative standard deviations of 1.2-4.0%.
Identifiants
pubmed: 34355865
doi: 10.1002/jssc.202100495
doi:
Substances chimiques
Deep Eutectic Solvents
0
Tetracyclines
0
Water Pollutants, Chemical
0
Thymol
3J50XA376E
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3626-3635Informations de copyright
© 2021 Wiley-VCH GmbH.
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