Photocatalyzed E→Z Contra-thermodynamic Isomerization of Vinyl Boronates with Binaphthol.
alkenes
binaphthol
boron
isomerization
photochemistry
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
07 Oct 2021
07 Oct 2021
Historique:
received:
13
07
2021
pubmed:
20
8
2021
medline:
20
8
2021
entrez:
19
8
2021
Statut:
ppublish
Résumé
The photocatalytic contra-thermodynamic E→Z isomerization of vinyl boronates by using a binaphthol catalyst is disclosed. The reaction, based on the transient formation of a suitable chromophore with a BINOL derivative as the catalyst, allowed geometrical isomerization in good-to-excellent Z/E ratio and excellent-to-quantitative yields. The mechanism of this E→Z contra-thermodynamic isomerization was studied, and the formation of a transient chromophore species is suggested.
Identifiants
pubmed: 34411357
doi: 10.1002/chem.202102536
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
13966-13970Informations de copyright
© 2021 Wiley-VCH GmbH.
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