Identifying Reactive Sites and Surface Traps in Chalcopyrite Photocathodes.

chalcopyrite density functional theory photoelectrochemistry spectroelectrochemistry water splitting

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
25 Oct 2021
Historique:
revised: 06 08 2021
received: 06 07 2021
pubmed: 25 8 2021
medline: 25 8 2021
entrez: 24 8 2021
Statut: ppublish

Résumé

Gathering information on the atomic nature of reactive sites and trap states is key to fine tuning catalysis and suppressing deleterious surface voltage losses in photoelectrochemical technologies. Here, spectroelectrochemical and computational methods were combined to investigate a model photocathode from the promising chalcopyrite family: CuIn

Identifiants

pubmed: 34428331
doi: 10.1002/anie.202108994
pmc: PMC8597141
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

23651-23655

Subventions

Organisme : schweizerischer nationalfonds zur förderung der wissenschaftlichen forschung
ID : PZENP2_166871
Organisme : schweizerischer nationalfonds zur förderung der wissenschaftlichen forschung
ID : PP00P2_157615
Organisme : gaznat-epfl research program
Organisme : china scholarship council
ID : CSC201806160172
Organisme : strategic japanese-swiss science and technology program
ID : 514259

Informations de copyright

© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

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Auteurs

Yongpeng Liu (Y)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, 1015, Switzerland.

Maria Bouri (M)

Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012, Bern, Switzerland.

Liang Yao (L)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, 1015, Switzerland.

Meng Xia (M)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, 1015, Switzerland.

Mounir Mensi (M)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, 1015, Switzerland.

Michael Grätzel (M)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, 1015, Switzerland.

Kevin Sivula (K)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, 1015, Switzerland.

Ulrich Aschauer (U)

Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012, Bern, Switzerland.

Néstor Guijarro (N)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Station 6, Lausanne, 1015, Switzerland.
Present address: Institute of Electrochemistry, Universidad de Alicante, Apartat 99, E-03080, Alacant, Spain.

Classifications MeSH