Stereodynamics of
NMR spectroscopy
crown ether
mechanically interlocked molecule
microscopic reversibility
molecular machine
molecular shuttle
nanoscience
non-equilibrium process
reaction mechanism
rotamer
Journal
Chem
ISSN: 2451-9294
Titre abrégé: Chem
Pays: United States
ID NLM: 101688902
Informations de publication
Date de publication:
12 Aug 2021
12 Aug 2021
Historique:
received:
18
11
2020
revised:
18
01
2021
accepted:
19
04
2021
entrez:
26
8
2021
pubmed:
27
8
2021
medline:
27
8
2021
Statut:
epublish
Résumé
The mechanical bond has opened a new world for structural and dynamic stereochemistry, which is still largely underexplored and whose significance for various applications is becoming increasingly evident. We demonstrate that designed rearrangements involving both covalent and mechanical bonds can be integrated in [2]rotaxanes, leading to interesting consequences in terms of
Identifiants
pubmed: 34435161
doi: 10.1016/j.chempr.2021.04.010
pii: S2451-9294(21)00211-4
pmc: PMC8367298
doi:
Types de publication
Journal Article
Langues
eng
Pagination
2137-2150Informations de copyright
© 2021 The Authors.
Déclaration de conflit d'intérêts
The authors declare no competing interests.
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