Tunable Quantum Photoinitiators for Radical Photopolymerization.
quantum confinement effect
quantum photoinitiators
semiconductor nanocrystals
upconverting nanoparticles
Journal
Polymers
ISSN: 2073-4360
Titre abrégé: Polymers (Basel)
Pays: Switzerland
ID NLM: 101545357
Informations de publication
Date de publication:
12 Aug 2021
12 Aug 2021
Historique:
received:
12
07
2021
revised:
30
07
2021
accepted:
03
08
2021
entrez:
28
8
2021
pubmed:
29
8
2021
medline:
29
8
2021
Statut:
epublish
Résumé
This review describes the use of nanocrystal-based photocatalysts as quantum photoinitiators, including semiconductor nanocrystals (e.g., metal oxides, metal sulfides, quantum dots), carbon dots, graphene-based nanohybrids, plasmonic nanocomposites with organic photoinitiators, and tunable upconverting nanocomposites. The optoelectronic properties, cross-linking behavior, and mechanism of action of quantum photoinitiators are considered. The challenges and prospects associated with the use of quantum photoinitiators for processes such as radical polymerization, reversible deactivation radical polymerization, and photoinduced atom transfer radical polymerization are reviewed. Due to their unique capabilities, we forsee a growing role for quantum photoinitiators over the coming years.
Identifiants
pubmed: 34451234
pii: polym13162694
doi: 10.3390/polym13162694
pmc: PMC8398557
pii:
doi:
Types de publication
Journal Article
Review
Langues
eng
Références
Nanoscale. 2019 Oct 7;11(37):17293-17300
pubmed: 31512703
Langmuir. 2010 Mar 2;26(5):3012-5
pubmed: 20102224
Angew Chem Int Ed Engl. 2018 Sep 10;57(37):12037-12042
pubmed: 30043508
Nanoscale. 2019 Jun 21;11(23):11209-11216
pubmed: 31157812
ACS Nano. 2020 Apr 28;14(4):4206-4215
pubmed: 32275814
J Phys Chem Lett. 2021 Feb 11;12(5):1520-1541
pubmed: 33534586
J Phys Chem B. 2015 Nov 19;119(46):14807-13
pubmed: 26492189
Nanoscale. 2017 Mar 23;9(12):4283-4294
pubmed: 28294258
Nano Lett. 2017 Jul 12;17(7):4497-4501
pubmed: 28617606
Adv Mater. 2018 Oct;30(41):e1706697
pubmed: 29656489
Langmuir. 2012 Dec 21;28(51):17795-802
pubmed: 23231028
Nanotechnology. 2015 Aug 7;26(31):315702
pubmed: 26177824
Nanomaterials (Basel). 2020 Oct 17;10(10):
pubmed: 33080773
J Am Chem Soc. 2021 Jun 30;143(25):9630-9638
pubmed: 34152140
ACS Appl Mater Interfaces. 2017 Sep 27;9(38):32418-32423
pubmed: 28876044
Nanoscale. 2021 Apr 21;13(15):7152-7160
pubmed: 33889919
Macromol Rapid Commun. 2014 Feb;35(4):454-9
pubmed: 24277641
Nano Lett. 2015 Aug 12;15(8):4985-92
pubmed: 26190135
J Colloid Interface Sci. 2019 Feb 15;536:149-159
pubmed: 30366180
Angew Chem Int Ed Engl. 2021 Mar 1;60(10):5489-5496
pubmed: 33179352
Polymers (Basel). 2021 Apr 01;13(7):
pubmed: 33915928
Photochem Photobiol. 2020 Jul;96(4):741-749
pubmed: 32115706
Sci Rep. 2018 Feb 26;8(1):3663
pubmed: 29483519
J Am Chem Soc. 2021 Jan 20;143(2):577-587
pubmed: 33353293
ACS Appl Mater Interfaces. 2020 Sep 16;12(37):42161-42168
pubmed: 32840349
Anal Chem. 2015 Feb 17;87(4):2383-8
pubmed: 25605399
Angew Chem Int Ed Engl. 2019 Feb 4;58(6):1828-1832
pubmed: 30511413
Sci Rep. 2013;3:1399
pubmed: 23466566
J Am Chem Soc. 2008 Jul 2;130(26):8280-8
pubmed: 18529003