Simultaneous determination of 11 quinolone residues in freshwater fish samples by magnetic solid-extraction coupled to liquid chromatography-tandem mass spectrometry.
freshwater fish
liquid chromatography-tandem mass spectrometry
magnetic solid-phase extraction
quinolone
trace analysis
Journal
Journal of separation science
ISSN: 1615-9314
Titre abrégé: J Sep Sci
Pays: Germany
ID NLM: 101088554
Informations de publication
Date de publication:
Nov 2021
Nov 2021
Historique:
revised:
19
08
2021
received:
13
07
2021
accepted:
23
08
2021
pubmed:
29
8
2021
medline:
16
2
2022
entrez:
28
8
2021
Statut:
ppublish
Résumé
In this study, well-defined core-shell ethylenediamine-functional magnetic ferroferric oxide polymers were prepared and were fully characterized by transmission electron microscopy, scanning electron microscopy, FTIR spectroscopy, and vibrating sample magnetometry. Then, it was used as a magnetic solid-phase extraction adsorbent for simultaneous determination of 11 trace quinolone residues in freshwater fish samples coupled to liquid chromatography-tandem mass spectrometry. The obtained results revealed that the adsorbent showed good extraction efficiency and the adsorption mechanisms referred to hydrogen bond and π-π stacking interaction. Moreover, the magnetic solid-phase extraction conditions were also carefully optimized. The limits of quantitation of 11 quinolones were in the range of 0.15-0.36 μg/kg, while spiking recoveries were in the range of 80.2-99.5% for the 11 quinolones in freshwater fish samples at four spiked levels including limits of quantitation, 1.0, 40.0, and 80.0 μg/kg with the relative standard deviations ranging from 0.8 to 9.1%. The proposed method was applied to analyze 45 freshwater fish samples, and enrofloxacin was detected in 91.1% samples with concentrations ranging from 0.659 to 333 μg/kg. It could be concluded that the proposed method is fast, simple, sensitive, and accurate for the routine monitor of freshwater fish.
Identifiants
pubmed: 34453397
doi: 10.1002/jssc.202100554
doi:
Substances chimiques
Quinolones
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4017-4024Subventions
Organisme : Zhejiang Provincial Natural Science Foundation
ID : LQ19B050001
Organisme : Ningbo Municipal Natural Science Foundation
ID : 2018A610404
Organisme : Ningbo Municipal Natural Science Foundation
ID : 2016A610178
Organisme : Ningbo Municipal Program for Leading and Top-Notch Talents, Zhejiang Province Basic Public Welfare Research Project
ID : LGN19H260001
Organisme : Ningbo Medical and Health Brand Discipline
ID : PPXK2018-10
Organisme : Zhejiang Provincial Key Disciplines of Medicine
ID : 07-013
Informations de copyright
© 2021 Ningbo municipal center for disease control and prevention. Journal of Separation Science published by Wiley-VCH GmbH.
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