Decarboxylative Hydroxylation of Benzoic Acids.
decarboxylation
ligand to metal charge transfer
phenol synthesis
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
02 11 2021
02 11 2021
Historique:
revised:
11
08
2021
received:
06
07
2021
pubmed:
1
9
2021
medline:
1
9
2021
entrez:
31
8
2021
Statut:
ppublish
Résumé
Herein, we report the first decarboxylative hydroxylation to synthesize phenols from benzoic acids at 35 °C via photoinduced ligand-to-metal charge transfer (LMCT)-enabled radical decarboxylative carbometalation. The aromatic decarboxylative hydroxylation is synthetically promising due to its mild conditions, broad substrate scope, and late-stage applications.
Identifiants
pubmed: 34464007
doi: 10.1002/anie.202108971
pmc: PMC8596882
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
24012-24017Informations de copyright
© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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