Chalcogen Bonds Involving Selenium in Protein Structures.


Journal

ACS chemical biology
ISSN: 1554-8937
Titre abrégé: ACS Chem Biol
Pays: United States
ID NLM: 101282906

Informations de publication

Date de publication:
17 09 2021
Historique:
pubmed: 4 9 2021
medline: 24 11 2021
entrez: 3 9 2021
Statut: ppublish

Résumé

Chalcogen bonds are the specific interactions involving group 16 elements as electrophilic sites. The role of chalcogen atoms as sticky sites in biomolecules is underappreciated, and the few available studies have mostly focused on S. Here, we carried out a statistical analysis over 3562 protein structures in the Protein Data Bank (PDB) containing 18 266 selenomethionines and found that Se···O chalcogen bonds are commonplace. These findings may help the future design of functional peptides and contribute to understanding the role of Se in nature.

Identifiants

pubmed: 34477364
doi: 10.1021/acschembio.1c00441
pmc: PMC8453483
doi:

Substances chimiques

Amino Acids 0
Chalcogens 0
Selenomethionine 964MRK2PEL
Fructokinases EC 2.7.1.-
fructokinase EC 2.7.1.4
Selenium H6241UJ22B

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1622-1627

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Auteurs

Oliviero Carugo (O)

Department of Chemistry, University of Pavia, 27100 Pavia, Italy.

Giuseppe Resnati (G)

Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, Via L. Mancinelli 7, 20131 Milano, Italy.

Pierangelo Metrangolo (P)

Department of Chemistry, Materials, and Chemical Engineering "Giulio Natta", Politecnico di Milano, Via L. Mancinelli 7, 20131 Milano, Italy.

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Classifications MeSH