Microwave pyrolysis of oily sludge under different control modes.
Control mode
Microwave pyrolysis
Oily sludge
Journal
Journal of hazardous materials
ISSN: 1873-3336
Titre abrégé: J Hazard Mater
Pays: Netherlands
ID NLM: 9422688
Informations de publication
Date de publication:
15 08 2021
15 08 2021
Historique:
received:
03
02
2021
revised:
09
04
2021
accepted:
10
04
2021
entrez:
8
9
2021
pubmed:
9
9
2021
medline:
18
9
2021
Statut:
ppublish
Résumé
The effects of temperature and power on product distribution and characteristics of oily sludge (OS) pyrolysis were investigated in a microwave reactor. The maximum oil yield was 72.55 wt% at 550 °C and 71.47 wt% at 800 W, respectively. X-ray photoelectron spectroscopy (XPS) indicated that C-C and C-O were the main forms of carbon in OS char (OC). The sulfur (S) content in OC increased as the temperature/power rose, implying that S might exist in the form of inorganics or OC had S retention ability. In temperature control mode, the changes of functional groups on OC surface were more sensitive. The maximum hydrocarbon content in oil was 14.56% at 350 °C and 13.40% at 900 W, respectively. The contents of oxygenated compounds and heterocycles in oil from temperature control mode were higher. The CO yield increased with increasing temperature/power, reaching the maximum of 9.60 wt% at 650 °C and 7.75 wt% at 900 W, respectively. Compared with power control mode, it seemed that more heavy metals (HMs) were retained in OC in temperature control mode. The E
Identifiants
pubmed: 34492825
pii: S0304-3894(21)00851-7
doi: 10.1016/j.jhazmat.2021.125887
pii:
doi:
Substances chimiques
Metals, Heavy
0
Sewage
0
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
125887Informations de copyright
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