Research on the Ash Melting Characteristics of Blended Coal Based on DFT Calculations.

Low-ash-melting-point bituminous coal and high-ash-melting-point anthracite coal are mixed and burned in different proportions. The ash melting characteristics of blended coal were determined experimentally. At the same time, the ash samples of bituminous coal, anthracite, and blended coal were analyzed by X-ray diffraction (XRD), and the ash melting characteristic improvement mechanism of blended coal was analyzed by quantum chemical calculations. The results show that when high-ash-melting-point anthracite is added, the ash melting characteristics of blended coal are improved, and the deformation temperature, softening temperature, hemispheric temperature, and flow temperature of the blended coal are significantly increased. The melting point of blended coal ash with a bituminous coal ratio of less than 50% can meet the requirements of blast furnace injection. The reason for the improved melting characteristics of the blended coal ash is that mullite in anthracite ash reacts with gehlenite in bituminous coal ash during the combustion process to produce anorthite.

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© 2021 The Authors. Published by American Chemical Society.

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The authors declare no competing financial interest.